How far? Flashcards

1
Q

what is dynamic equilibrium?

A

when the forward reaction is happening at the same speed as the backwards reaction, so there is no overall change in concentration

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2
Q

what does le chateliers principle say

A

when a system is in dynamic equilibrium is subjected to a change, the position of the equilibrium will shift to minimine the change.

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3
Q

what happens to the equilbirum when you raise the temperature

A

the quilibrium move in the endothermic direction

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4
Q

what happens to the equilbirum when you decrease the temperature

A

equilibrium moves in the endothermic direction

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5
Q

what happens to the equilbirum when you raise the pressure

A

equilibrium moves to the side with fewer moles of gas to reduce the pressure

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6
Q

what happens to the equilbirum when you deacrese the pressure

A

equlibirium moves to the side with more moles of gas to increase the presure

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7
Q

what happens to the equilbirum when you add a catalyst

A

quiliibrum doesnt change, the rate of the forward and backwards reaction both increase equally

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8
Q

what is Kc?

A
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9
Q

is kc product over reactant?

A

yes

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10
Q

what is the concentration to the power of in kc?

A

balancing numbers

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11
Q

Kc is constant unless you do what?

A

CHANGE THE TEMPERATURE

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12
Q

What is concentration?

A

the amount of solute in moles per 1dm^3 of solution

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13
Q

what does it mean if something is homeogeneous?

A

the ractnats, products and catalysy are all in the same phase

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14
Q

what to say if units cancel out?

A

no units

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15
Q

what does it mean if something is heterogeneous?

A

reactants, products and catalyst are not in the same phase.

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16
Q

what do we do when writing Kc equation for aqueous solutions

A

include H2O (l) if being reacted (unless everythign else is aq)

Other than that should be only (aq)

Ignore all solids

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17
Q

-what do we do when writing Kc equation for gaseous reactions?

A

only include gases

ignore all solids and liquids

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18
Q

what does it mean if a reaction is homogeneous?

A

reactants, products and catalsysts are all in the same phase

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19
Q

what does it mean if a reaction is heterogeneous?

A

reactants, products and catalyst are in different phases

20
Q

what does it mean if Kc is greater than 1?

A

There are more products and the POE layhs to the right

21
Q

what does it mean if Kc is less than 1?

A

there are more reactants, and teh POE lays to the left

22
Q

what does it mean if Kc is 0?

A

there are approximately the same amount of products and reactatns and the equilibrium is balanced

23
Q

What do we say if we have a higher value of Kc?

A

equilibrium lays further to the right: more products at equilibrium

24
Q

what doe we say baout lower values fo Kc?

A

equilibrium lays further to the leftt: more reactatns/fewer products at equilibrium

25
how do we find out kc when we are given the moles?
we work out the concentration of each mol/total volume plug into Kc expression
26
when there is not volumes given, and Kc has no units, how do we work out Kc?
The volumes cancel out, so just uses the moles instead of the concentrauion
27
what do we use for harder Kc equatuion?
We use an ICE(E) table Initial mol Change in Mol Equilibrium mol Equilibrium concentraion
28
what is Partial pressure?
The contribution the gas makes to the total pressure
29
how to work out mole fraction?
30
what is partrial pressure of a gas in a micture equal to?
mole fraction x total pressure
31
what are two important conclusions about partial pressures?
All the mole fractions add up to one All the partial pressure ass up to the total pressure
32
write Kp for H2 and N2
33
what do we use to calculatae Kp for harder equations?
We use an ICE table Initial mol change in mol equilibrium mol mol fraction (equilibrium moel of x/total equilbrium moles) partial pressure (mole fraction x total pressure)
34
what to do when a mixture contains a % of a gas?
convert the % into a mole fraction by dividing by 100
35
what to do when given the partial pressure of two of three gasses?
total pressure - partial pressure A- partial pressure B
36
What to do wehn a question states at pressure X, A is 50% dissociated. calualte Kp
the equilibrum concentrion of A should be 50.
37
What happens to Kc and Kp of an endothermic reaction when there is a temperature change?
increase: Kc and Kp increase Decrease: Kp and Kc decrease
38
What happens to Kc and Kp of an exothermic reaction when there is a temperature change?
increase: Kp and Kc decrease decrease: Kp and Kc increase
39
When does Kc and Kp change?
WHEN THERE IS A TEMPERATURE CHANGE
40
what can you say about Kc when there are changes in temperature?
Kc gets bigger or small leading to a shift in the position of equilibrium
41
what can we say about Kc when there are changes in concentraiotn of reactants or products?
Kc is constant, so there has to be a change in then position of the equilibrium
42
what do we say about Kc when there is a change in the pressure for some gas reactions?
Kc is constant, so there has to be a change in then position of the equilibrium
43
How Kc and Kp shift the position of the equilibrium when concentraions change
44
How Kc and Kp shift the position of equilibrium when temperature changes
45
how Kc and Kp shift the position of the equilibrium when pressure changes
46
What effect does a catalyst have on Kc and the position of equilibrium?
None