Higher: C5 - Energy changes Flashcards

1
Q

What is an exothermic reaction?

A

One which transfers energy to the thermal energy store of the surroundings.

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2
Q

Give 3 examples of exothermic reactions.

A

Combustion, neutralisation and many oxidation reactions.

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3
Q

Give 2 everyday uses of exothermic reactions.

A

Self-heating cans and hand warmers.

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4
Q

What is an endothermic reaction?

A

One which takes energy from, and decreases the thermal energy store of, the surroundings.

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5
Q

Give 2 examples of endothermic reactions.

A

Thermal decomposition, and the reaction between citric acid and sodium hydrogencarbonate.

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6
Q

Give one use of an endothermic reaction.

A

Sports injury packs.

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7
Q

Describe how you could test the effect of concentration of HCl on the energy released in a neutralisation between HCl and NaOH.

A

1) Place equal volumes of HCl and NaOH (of equal concentrations) in beakers.
2) Put these in a water bath at a set temperature and wait for them to reach this.
3) To minimise energy lost to the surroundings, line a beaker with cotton wool and put a polystyrene cup inside it.
4) Add the HCl and NaOH to the cup and place a lid on it, recording the starting temperature w/ a thermometer.
5) Record the temperature every 20 seconds until the temperature stops increasing.
6) Repeat steps 1-5 with different concentrations of HCl, and repeat each stage 3 times to find an average.

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8
Q

Is the process of breaking bonds exothermic or endothermic, and why?

A

Endothermic, because it takes energy to overcome the forces holding together the bonds.

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9
Q

Is the process of forming bonds exothermic or endothermic, and why?

A

Exothermic, because particles become more stable when they form compounds.

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10
Q

Why do exothermic reactions release energy to the surroundings?

A

The energy released by forming bonds is greater than the energy used to break them.

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11
Q

Why do endothermic reactions take energy from the surroundings?

A

The energy used to break bonds is greater than the energy released by forming them.

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12
Q

What is the activation energy of a reaction?

A

The minimum amount of energy that particles must have to react.

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13
Q

What are reaction profiles?

A

Diagrams that show the changes in the relative energies of the reactants and products of a reaction. The progress of the reaction is plotted against energy.

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14
Q

Draw a reaction profile for an exothermic reaction.

A
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15
Q

Draw a reaction profile for an endothermic reaction.

A
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16
Q

Using the bond energies given below, calculate the energy change for the reaction between hydrogen and chlorine forming hydrochloric acid.

  • H–H = +436kJ/mol
  • Cl–Cl = +242kJ/mol
  • H–Cl = +431kJ/mol
A
  1. Symbol equation: H2 + Cl2 →2HCl
  2. Find energy needed to break original bonds: 436 + 242 = 678kJ/mol
  3. Find energy released by making new bonds: 2 x 431 = 862kJ/mol
  4. Find overall energy change: 678 - 862 = -184kJ/mol