Hexaaqua Ions Flashcards

1
Q

What happens when Na2CO3 is added to [Fe(H2O)6]3+ ?

A
  • [Fe(H2O)3(OH)3] formed
  • brown precipitate
  • bubbles of CO2 gas
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2
Q

What happens when concentrated HCl is added in excess to [Al(H2O)6]3+ ?

A
  • [AlCl4]-
  • colourless solution
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3
Q

What happens when NH3(aq) is added dropwise to [Al(H2O)6]3+ ?

A
  • [Al(H2O)3(OH)3] formed
  • white precipitate
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4
Q

What happens when NaOH(aq) is added in excess to [Al(H2O)6]3+ ?

A
  • [Al(H2O)2(OH)4]- formed
  • re-dissolves to give a colourless solution
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5
Q

What happens when concentrated HCl is added to [Fe(H2O)6]3+ ?

A
  • [FeCl4]- formed
  • yellow solution
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6
Q

What happens when NaOH(aq) is added in excess to [Fe(H2O)6]3+) ?

A
  • no further reaction
  • brown precipitate
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7
Q

What happens when NaOH(aq) is added dropwise to [Fe(H2O)6]3+) ?

A
  • [Fe(H2O)3(OH)3] formed
  • brown precipitate
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8
Q

What happens when concentrated HCl is added in excess to [Cu(H2O)6]2+ ?

A
  • [CuCl4]2- formed
  • green solution
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9
Q

What happens when Na2CO3(aq) is added in excess to [Cu(H2O)6]2+ ?

A
  • CuCO3 formed
  • blue-green precipitate
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10
Q

What happens when NH3(aq) is added in excess to [Cu(H2O)6]2+ ?

A
  • [Cu(H2O)2(NH3)4]2+ formed
  • deep blue solution
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11
Q

What happens when NH3(aq) is added dropwise to [Cu(H2O)6]2+ ?

A
  • [Cu(H2O)4(OH)2] formed
  • blue precipitate
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12
Q

What happens when NaOH(aq) is added in excess to [Cu(H2O)6]2+ ?

A
  • no further reaction
  • blue precipitate
  • [Cu(H2O)4(OH)2]
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13
Q

What happens when NaOH(aq) is added dropwise to [Cu(H2O)6]2+ ?

A
  • [Cu(H2O)4(OH)2] formed
  • blue precipitate
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14
Q

What happens when Na2CO3(aq) is added to [Fe(H2O)6]2+ ?

A
  • FeCO3 formed
  • green precipitate
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15
Q

What happens when NH3(aq) is added in excess to [Fe(H2O)6]2+ ?

A
  • no further reaction
  • green precipitate
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16
Q

What happens when NH3(aq) is added dropwise to [Fe(H2O)6]2+ ?

A
  • [Fe(H2O)4(OH)2] forms
  • green precipitate
  • (darkens on standing due to oxidation to [Fe(H2O)3(OH)3])
17
Q

What happens when NaOH(aq) is added in excess to [Fe(H2O)6]2+ ?

A

no further reaction
- green precipitate (that darkens on standing)

18
Q

What happens when NaOH(aq) is added dropwise to [Fe(H2O)6]2+) ?

A
  • [Fe(H2O)4(OH)2] forms
  • green precipitate
    (darkens on standing due to oxidation to [Fe(H2O)3(OH)3])
19
Q

What are [Cu(H2O)6]2+ ions like in aqueous solution?

A

blue solution

20
Q

What are [Fe(H2O)6]2+ ions like in aqueous solution?

A

green solution

21
Q

What happens when NaOH(aq) is added dropwise to [Al(H2O)6]3+ ?

A
  • [Al(H2O)3(OH)3] formed
  • white precipitate
22
Q

What happens when concentrated HCl is added to [Fe(H2O)6]2+ ?

A
  • [FeCl4]2- formed
  • yellow solution
23
Q

What happens when NH3(aq) is added in excess to [Fe(H2O)6]3+ ?

A
  • no further reaction
  • brown precipitate
24
Q

What are [Fe(H2O)6]3+ ions like in aqueous solution?

A

pale violet solution (but appears orange due to hydrolysis to some [Fe(H2O)5(OH)]2+ ions)

25
What happens when NH3(aq) is added in excess to [Al(H2O)6]3+ ?
- no further reaction - white precipitate
26
What happens when NH3(aq) is added dropwise to [Fe(H2O)6]3+ ?
- [Fe(H2O)3(OH)3] formed - brown precipitate
27
What are [Al(H2O)6]3+ ions like in aqueous solution?
colourless solution
28
What happens when Na2CO3(aq) is added to [Al(H2O)6]3+ ?
- [Al(H2O)3(OH)3] formed - white precipitate and bubbles of of CO2 gas