Group 7 Flashcards
how to test for halide ions
nitric acid and add silver nitrate
what are the positive results of testing for halide ions
AgCl - white
AgBr - cream
AgI - yellow
how to determine what halide ion is present as a compound with Ag in an unknown solution
AgCl = dissolves in dilute ammonia
AgBr = dissolves in conc. ammonia
AgI = does not dissolve
What type of agents are halide ions?
reducing
What type of agents are halogens?
oxidising
What are the weakest reducing agents?
F + Cl
What is the acid-base reaction of F to produce a hydrogen halide?
NaF(s) + H2SO4(l) -> NaHSO4(s) + HF(g)
What is the acid-base reaction of Cl to produce a hydrogen halide?
NaCl(s) + H2SO4(l) -> NaHSO4(s) + HCl(g)
What is the strongest reducing agent?
I-
What is the acid-base reaction of Br to produce a hydrogen halide?
NaBr(s) + H2SO4(l) -> NaHSO4(s) + HBr(g)
What is observed when Florine and Chlorine produce hydrogen halides?
steamy white fumes
What is observed when bromine produces a hydrogen halide?
orange fumes
What is the redox reaction of the Br- to Br2 in the acid base reaction?
2H+ + 2Br- + H2SO4 ->Br2 + SO2 + 2H2O
What is the overall equation of Br2 reacting with sulfuric acid?
2NaBr(s) + 3H2SO4(l) -> 2NaHSO4(s) + SO2(g) +2H2O(g)
What is the acid-base reaction of I to produce a hydrogen halide?
NaI(s) + H2SO4(l) -> NaHSO4(s) + HI(g)
What is the redox reaction of the I- to I2 and produces SO2 in the acid-base reaction?
2H+ + 2I- + H2SO4 ->I2 + SO2 + 2H2O
What is the observation of the acid-base reaction of I?
white misty fumes
What is the observation of the redox reaction reaction of I- to I2(s)?
black solid
What is the observation of the redox reaction reaction of I- to I2(g)?
purple fumes
What is the redox reaction of the I- to I2 and produces S(s) in the acid-base reaction?
6H+ + 6I- + H2SO4 -> 3I2 + S + 4H2O
What is the redox reaction of the I- to I2 and produces H2S in the acid-base reaction?
8H+ + 8I- + H2SO4 -> 4I2 + H2S + 4H2O
What observation can be made when S is formed?
yellow ppt
What observation can be made when H2S is formed?
gas with bad egg smell
What is a disproportionation reaction?
where an element oxidises and reduces in the same reaction