Group 7 Flashcards

1
Q

how to test for halide ions

A

nitric acid and add silver nitrate

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2
Q

what are the positive results of testing for halide ions

A

AgCl - white
AgBr - cream
AgI - yellow

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3
Q

how to determine what halide ion is present as a compound with Ag in an unknown solution

A

AgCl = dissolves in dilute ammonia
AgBr = dissolves in conc. ammonia
AgI = does not dissolve

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4
Q

What type of agents are halide ions?

A

reducing

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5
Q

What type of agents are halogens?

A

oxidising

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6
Q

What are the weakest reducing agents?

A

F + Cl

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7
Q

What is the acid-base reaction of F to produce a hydrogen halide?

A

NaF(s) + H2SO4(l) -> NaHSO4(s) + HF(g)

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8
Q

What is the acid-base reaction of Cl to produce a hydrogen halide?

A

NaCl(s) + H2SO4(l) -> NaHSO4(s) + HCl(g)

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9
Q

What is the strongest reducing agent?

A

I-

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10
Q

What is the acid-base reaction of Br to produce a hydrogen halide?

A

NaBr(s) + H2SO4(l) -> NaHSO4(s) + HBr(g)

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11
Q

What is observed when Florine and Chlorine produce hydrogen halides?

A

steamy white fumes

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12
Q

What is observed when bromine produces a hydrogen halide?

A

orange fumes

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13
Q

What is the redox reaction of the Br- to Br2 in the acid base reaction?

A

2H+ + 2Br- + H2SO4 ->Br2 + SO2 + 2H2O

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14
Q

What is the overall equation of Br2 reacting with sulfuric acid?

A

2NaBr(s) + 3H2SO4(l) -> 2NaHSO4(s) + SO2(g) +2H2O(g)

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15
Q

What is the acid-base reaction of I to produce a hydrogen halide?

A

NaI(s) + H2SO4(l) -> NaHSO4(s) + HI(g)

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16
Q

What is the redox reaction of the I- to I2 and produces SO2 in the acid-base reaction?

A

2H+ + 2I- + H2SO4 ->I2 + SO2 + 2H2O

17
Q

What is the observation of the acid-base reaction of I?

A

white misty fumes

18
Q

What is the observation of the redox reaction reaction of I- to I2(s)?

A

black solid

19
Q

What is the observation of the redox reaction reaction of I- to I2(g)?

A

purple fumes

20
Q

What is the redox reaction of the I- to I2 and produces S(s) in the acid-base reaction?

A

6H+ + 6I- + H2SO4 -> 3I2 + S + 4H2O

21
Q

What is the redox reaction of the I- to I2 and produces H2S in the acid-base reaction?

A

8H+ + 8I- + H2SO4 -> 4I2 + H2S + 4H2O

22
Q

What observation can be made when S is formed?

A

yellow ppt

23
Q

What observation can be made when H2S is formed?

A

gas with bad egg smell

24
Q

What is a disproportionation reaction?

A

where an element oxidises and reduces in the same reaction

25
What is the reaction of Chlorine and water?
Cl2(g) + H2O(l) -> HClO(aq) + HCl(aq)
26
What is the reaction of Chlorine and water with sunlight?
Cl2(g) + H2O(l) -> 4H+ +4Cl- + O2
27
How is bleach made?
Cl2(aq) + 2NaOH(aq) -> NaCl(aq) + NaClO(aq) + H2O(l)
28
What observation can be made when bleach is made?
green -> colourless