HAZMAT MANUAL Flashcards
An Incident Site Safety Plan will be prepared and reviewed by the Hazmat Director or designee for each hazmat response. This form will be sent to the Command Post within ________ of arrival of Hazmat Unit.
30 min
This Incident Site Safety Plan should be delivered to the IC within _______ of the Hazmat Unit’s arrival on scene.
30 minutes
Training shall be based on the duties and functions to be performed by each __________ of the OKCFD. The training will conform to: _____________.
Responder, 29 CFR 1910.120 q, 3, 4, 6, I and NFPA 472.
OKCFD shall deliver First Responder Awareness and Operations level training to personnel within _______ of employment and prior to deployment in any active emergency response operations.
90 days
OKCFD First responders at the operational level shall have received at least _________, and shall be able to objectively demonstrate competence.
40 hours of training
To command a site it is necessary to control the site by limiting the number of personnel to the site (Zones). There should be at least ______;_____with larger more complex incidents between the CP and the Hazmat Team, this will allow both ______ and the ___________ to perform their operations.
100feet;200 feet
IC
Hazmat Team
Establish a ________ to isolate the area. Use two cones spread approx. 30 feet apart and _________ from the tailboard of the first-arriving engine company. Isolate the area. Deny access to non-emergency responders.
Control Line, 80-100 feet
When permanently assigned hazardous materials personnel are scheduled off on their duty day, the Hazmat Team shall not be permitted to drop below ____ persons, minimum of ____ hazardous materials person at Station 5.
4, 7
A Level 1 incident is defined as a release of less than ______ of a liquid or less than ______ of a solid of a known hazardous material.
10 gallons, 20 pounds
A Level II incident is defined as a release of ________ of a liquid or _________ of a solid of a known hazmat OR the release of ____________ liquid, solid, or gaseous material that is toxic (all gasses other than NG or LPG shall be considered as toxic), corrosive, poisonous, reactive, or radioactive.
10 or more gallons, 20 pounds or more,
any quantity of an unknown
Examples of Level II incident: Fires in buildings with a 704 rating of ________ in any category.
2 or greater
ON-SITE PROCEDURES
Medical Surveillance: If temperature is above _____ a mandatory heat stress evaluation and pre-entry medical evaluation will be performed.
70 degrees F
HAZMAT TEAM - RESPONSE LEVELS
Level II Task Force Staffing
– _____ trained personnel
12
A Level II is a threat to the __________and/or ________ humans.
Environment, Endangers
A Level III incident is _____________.
Life-threatening
Basic Decontamination will consist of a minimum _____ flush administered with a booster nozzle or sufficient water supply. There are ___ exceptions to this minimum practice.
60 sec, NO
HAZMAT TEAM - SITE CONTROL
Setting Zones: This zone should be a minimum of ____ feet for bulk packaging (liquid-internal volume of more than ____ gal, solid-capacity of more than ____ pounds, compressed gas-water capacity of more than _____ pounds(___ gals), OR ____ feet for non-bulk packaging unless otherwise stated.
500 ft, 119 gals, 882 lbs, 1001 lbs, (120gals),
200 ft
HAZMAT TEAM - IDENTIFYING THE HAZARD
- Type of facility and what is manufactured there. Such as: paint supply, farm and garden, fuel distributor, hardware store, etc.
Occupancy and Location
HAZMAT TEAM - IDENTIFYING THE HAZARD
- The location of incident in relation to exposures.
Occupancy and Location
HAZMAT TEAM - IDENTIFYING THE HAZARD
- Pressure or non-pressure container.
- Portable tanks, cargo tanks rail tank-car, cylinder.
- Special containers may carry special products.
Container Shapes
HAZMAT TEAM - IDENTIFYING THE HAZARD
Marking numbers that designates a UN/NA Hazmat if some kind.
Markings and Colors
HAZMAT TEAM - IDENTIFYING THE HAZARD
- DOT placards
- NFPA 704M
- United Nations Hazard Class Numbers
- HMIS Labels
Placards and Labels
HAZMAT TEAM - IDENTIFYING THE HAZARD
Data sheets may come in the form of Shipping papers, Material Safety Data Sheets (MSDS), and/or Manifests.
- Only retrieve shipping papers if you are able to stay out of the product and it's vapors. - Approach upwind.
Chemical Data Sheets
HAZMAT TEAM - IDENTIFYING THE HAZARD
- Determine what products are manufactured or stored on site.
- If they have been contaminated, find out their symptoms and what the physical state(s) of the products are, solid, liquid, gas, what type of odor, what color, etc.
Facility Personnel
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 1
Explosives
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 2 (________, __________, & ________)
Gases (Flammable, Nonflammable, & Poison)
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 2: You have about __ min of fire impingement above the liquid line before a BLEVE can be expected.
5 min
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 2: A flow of ___ gpm will be needed to protect the container from failure; the flow should come from __________ gpm lines. This will cover a wider container surface than _________gpm line.
500 gpm, two (2) 250 gpm, one (1) 500 gpm
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 3
Flammable and Combustible Liquiids
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 3: If the Flammable Liquids are leaking from a Highway Cargo Tank, a ___ ft zone should be established.
500 ft
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 3: The application of _______ from a safe distance is acceptable.
Foam
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 4
Flammable Solids, Spontaneously Combustible & Dangerous When Wet
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 4: Do not fight Flammable Solids and Pyrophoric fires as they ___________________.
May react when applying water.
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 5
Oxidizers and Organic Peroxides
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 5: ______ quantities (up to __lbs) on fire can be extinguished by water.
Small, 10 lbs
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 6
Poisons and Infectious Substances
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 6: Do not fight Poisonous fires above ___ gallons.
55
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 7
Radioactives
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 7: Do not fight any Radiation fires in ______ packaging.
Bulk type
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 8
Corrosives
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 8: ______ quantities (up to ___ gals) may be diluted with water, in an attempt to control reaction between corrosive and additional products.
Small, 5 gals
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 8: Do not attempt to try and dilute the product if over ___ gallons.
5
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 8: If corrosive is on fire, protect __________ and let the corrosive consume itself.
Exposures
HAZMAT TEAM - IDENTIFYING THE HAZARD
CLASS 9
Miscellaneous Materials
HAZMAT TEAM - IDENTIFYING THE HAZARD
Limited Availability of Information:
- If the product/chemicals name ends in ___ or ___, use caution when _____________.
IDE, IUM, using water.
HAZMAT TEAM - IDENTIFYING THE HAZARD
Limited Availability of Information
- Use Guide ____ in the _____.
111, NAERG
HAZMAT TEAM - IDENTIFYING THE HAZARD
Limited Availability of Information
- If the container has a refrigeration unit and is placarded……
DO NOT fight the fire.
HAZMAT TEAM - EVACUATION PROCEDURES
- provides a transition between contaminated and clean zones.
Warm Zone
HAZMAT TEAM - EVACUATION PROCEDURES
WARM ZONE:
- Initially this zone is considered a _____________ area.
Non-contaminated
HAZMAT TEAM - EVACUATION PROCEDURES
WARM ZONE:
-The _________________ (Decon) will be located in this zone.
Contamination reduction corridor
HAZMAT TEAM - EVACUATION PROCEDURES
WARM ZONE:
- All people entering the ______________ must wear the prescribed levels of protection.
Contamination Reduction Zone
HAZMAT TEAM - EVACUATION PROCEDURES
WARM ZONE:
- All _______________ will stay in this zone.
Contaminated equipment
HAZMAT TEAM - DECONTAMINATION PROCEDURES
The decontamination area will be established within the ______________.
Contamination Reduction Zone (Warm Zone)
HAZMAT TEAM - DECONTAMINATION PROCEDURES
What 4 techniques are used to Decon personnel, equipment and supplies?
- Dilution
- Absorption
- Chemical Degradation
- Isolation
HAZMAT TEAM - DECONTAMINATION PROCEDURES
- The _____________ shall be used during decon operations and shall include provision for ______, ________ and __________ of non-essential private items. ( rings, watches, wallets, jewelry, etc.) from entry team members.
Decontamination Checklist, removal, identification and secure storage
HAZMAT TEAM - DECONTAMINATION PROCEDURES
What are the 9 steps of the Decontamination Checklist?
Step 1 - Establish an Entry Point Step 2 - Primary Decontamination Step 3 - SCBA Removal Step 4 - Removal & Isolation of Protective Clothing Step 5 - Removal of Personal Clothing Step 6 - Decontaminating the Body Step 7 - Drying off and Providing Clean Clothing Step 8 - Medical Evalaution Step 9 - Transportation
DEFINITION
- the immediate removal of contaminate from an employee using a minimum 60 sec flush with soap if available and water. Then take the affected people to the area of refuge.
Basic Decontamination Procedure
DEFINITION
- Chemical reaction with the release of energy. Undesirable effects, such as pressure buildup, temperature increase, and formation of noxious, toxic or corrosive by-products may occur because of the reactivity of a substance to heating burning, direct contact with other materials, or other conditions in use or in storage.
Reactivity
DEFINITION
- the weight of a material compared to the weight of an equal volume of water is an expression of the density (or heaviness) of a material. Insoluble materials with specific gravity of less than 1.0 will float in (or on) water. Insoluble materials with specific gravity greater than 1.0 will sink in water. Most (but not all) flammable liquids have specific gravity less than 1.0 and, if not soluble, will float on water, which is an important consideration for fire suppression.
Specific Gravity
DEFINITION
- the weight of a vapor or gas compared to the weight of an equal volume of air is an expression of the density less than 1.0 (examples: acetylene, methane, hydrogen). Materials heavier than air (examples: propane, hydrogen sulfide, ethane, butane, chlorine, sulfur dioxide) have vapor densities greater than 1.0. All vapors and gases are likely to concentrate in low places along or under floors, in sumps, sewers, and manholes, in trenches and ditches where they may create fire or health hazards.
Vapor Density
DEFINITION
- the pressure exerted by a saturated vapor above its own liquid in a closed container. When quality control tests are performed on products, the test temperature is usually 100F, and the vapor pressure is expressed as psi, but vapor pressures reported on MSDS are in millimeters of mercury (mmhg) at 68F (20*C), unless stated otherwise.
Vapor pressure
Three Important Facts for Vapor Pressure:
1) Vapor pressure of a substance at 100*F will always be \_\_\_\_\_\_\_\_ than the vapor pressure of the substance at 68*F.
Higher
Three Important Facts for Vapor Pressure:
2) Vapor pressure reported on MSDS in mmhg are usually \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_; 760 mmhg is the equivalent to 14.7 psi.
Very low pressures
Three Important Facts for Vapor Pressure:
3) The \_\_\_\_\_\_\_\_ the boiling point of a substance, the \_\_\_\_\_\_\_\_\_ it's vapor pressure.
Lower, higher
DEFINITION:
- an IDLH condition, a place of great contamination danger. After being in the _____________ zone Decon is absolutely necessary.
Exclusion Zone