Halogens Flashcards

1
Q

What are the group 7 elements?

A

Chlorine, Florine Iodine and Bromine

~they exist as diatomic

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2
Q

What are the different types of halite ions?

A

Bromide
Chloride
Iodide

  • they exist as single ions with a charge -1
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3
Q

Reactivity series of halogens?

A
  1. 2.
    3.

*More reactive halogen displaces weaker halogens

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4
Q

What colour is produced when chlorine and KBR reacts? Why does it change this color? Give equation ionic/symbol:

A

Orange solution - Because bromine is the product in the reaction

{ Cl2 + 2KBR -> Br2 + 2KCL }

ionic: { Cl2 + Br-
- -> Br2 + 2Cl-}

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5
Q

What happens when chlorine and potassium iodine?

A

Brown solution

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6
Q

What happens when bromine reacts with potassium iodide?

A

Brown Solution

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7
Q

What is the formation of bleach?

A

2NaOH + Cl2 –> NaClO + NaCl +

H20

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8
Q

What is bleach used for?

A

Cleaning

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9
Q

What is a disproportionation reaction?

A

Is a reaction were same thing is oxidized and reduced

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10
Q

What is the word equation for chlorine and water?

A

Cl2 + H20 ⇌ HClO (chloric 1 acid) + HCl

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11
Q

Why is chlorine used to treat water?

A

They benefit outweighs the risk

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12
Q

Why is chlorine used to treat water?

A

It kills bacteria making it clean preventing spread of disease

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13
Q

What are the disadvantages of using chlorine to treat water?

A

It is toxic

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14
Q

What is a reducing agent?

A

a substance that tends to bring about reduction by being oxidized and losing electrons.

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15
Q

Are halides reducing agents?

True/False

A

True

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16
Q

What happens when halide and sulfuric acid reacts?

A

metal halide + sulfuric acid —> metal sulfate + hydrogen halide

e.g.

NaCl + H2SO4 –> NaHSO4 + HCl

17
Q

Why is a reaction between metal halides and sulfuric acid non redox?

A

This is because there no change in oxidation states

18
Q

What is released between a reaction with sulfuric acid and metal halide?

A

Misty White Fumes

19
Q

What happens during reaction of hydrogen bromine and sulfuric acid?

A

2HBr + H2SO4 —-> Br2 + SO2 + 2H20

20
Q

Is hydrogen bromide and sulphric acid a redox reaction?

TRUE/ FALSE

A

TRUE

21
Q

What happens when you react hydrogen halide and sulfuric acid?

A

hydrogen halide + sulfuric acid —> halogen + sulfuric oxide + water

e.g.

2HI + H2SO4 —> I2 + SO2 + 2H20

22
Q

What happens when you react hydrogen halide and sulfur oxide?

A

hydrogen halide + sulfur oxide –> hydrogen halide + halogen + water

e.g.

6HI + SO2 –> H2S + 3I2 + 2H20

23
Q

How do you test for halides?

A

Add Nitric Acid (HNO3) and Silver Nitrate (AgNO3)

If present:
Chlorine - White precipitate

Iodide - Yellow Precipitate

You can conduct an ammonia (NH3) test:

Chlorine - dissolves in dilute ammonia

Bromine - dissolves in concentrated ionic ammonia

Iodine - does not dissolve in ammonia

24
Q

What is the the generic symbol equation for halide test?

A

Ag+ (+) X- —-> AgX

X = Halide

25
Q

Halogen order according to reducing power

A
  1. Iodine (Largest)
  2. Bromine
  3. Chlorine (Weakest)
26
Q

What is the trend in boiling point as you go down group 7? Why?

A

The boiling point increases - this is because van der walls forces increase due to the increasing size and relative mass of atoms

27
Q

How does states change as you go down group 7?

A

gas at the top and solid at the bottom

28
Q

How does electronegativity change as you go down the group? Why?

A

As you go down elecronegativity decreases - This is because the larger the atom the distance between positive nucleus and bonding electrons increase know as shielding

29
Q

What is electronegativty?

A

Is the ability for an atom to attract electrons towards its’ covalent bond

30
Q

What happens with reactivity as you go down group 7?

A

Reactivity decreases