halogens Flashcards

1
Q

bromine

A

Br2

brown orange liquid

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2
Q

iodine

A

I2

grey solid

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3
Q

fluorine

A

F2

pale yellow gas

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4
Q

chlorine

A

Cl2

pale green gas

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5
Q

group 7 halogen

A

will displace a halide from solution if the halide is lower in the periodic table

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6
Q

disproportion- ation reaction

A

when something is being simultaneously reduced and oxidised

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7
Q

potassium iodide + iodine solution

A

no reaction

equally as reactive so nothing can be displaced

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8
Q

potassium bromide + iodine solution

A

no reaction

KBr is less reactive than iodine

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9
Q

advantages of adding chlorine to drinking water

A

destroys microorganisms that cause diseases

long lasting so reduces bacteria build up

reduces growth of algae that discolours water and gives a bad taste/smelll

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10
Q

disadvantages of adding chlorine to drinking water

A

chlorine gas is toxic and irritates respiratory system

liquid chlorine can cause chemical burns to skin

Cl2 can react with organic compounds to make chloroalkanes which causes cancer

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11
Q

reducing power of halide ions

A

reducing agents (loses an e-)

ionic radius increases

distance between nucleus and outer e- become larger (more shielding)

outer e- is more readily

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12
Q

potassium bromide + chlorine water

A

forms an orange solution

Cl2+2Br- —2Cl-+Br2

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13
Q

potassium chloride + iodine solution

A

no reaction

iodine is less reactive than chlorine so can’t displace

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14
Q

potassium iodide + bromine water

A

forms brown solution

Br2+2I- — 2Br- +I2

bromine is more reactive than iodine

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15
Q

potassium bromide + bromine water

A

no reaction because 2 bromines are reacting together

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15
Q

potassium chloride + bromine water

A

no reaction

bromine is less reactive than chlorine so displacement reaction can’t take place

16
Q

potassium iodide + chlorine water

A

forms brown solution

Cl2+2I- —2Cl- +I2

chlorine reacts with iodine

iodine displaced chlorine ions

17
Q

potassium chloride + chlorine water

A

no reaction because 2 chlorines are reacting together

18
Q

uses of sodium chlorate

A

treating water

bleaching paper or fabric

cleaning agents (bleach)

19
Q

equation for bleach

A

2Na(aq)+Cl2(g) — NaClO(aq) + NaCl(aq) + H2O(l)

20
Q

reactivity trend

A

decreases

for a reaction to occur an e- has to be gained

smaller radius attracts e- better than larger atoms

21
Q

electronegativity trend

A

decreases

atoms get bigger

distance between positive nucleus. and bonding e- increases

more shielding

22
Q

boiling point trend

A

increases

van de waals forces increase

size and relative mass of atoms increases

gas — solid (not liquids)

23
Q

testing for cations (flame test)

A
  1. dip the nichrome wire with concentrated HCl
  2. dip into sample
  3. place the loop into a blue bunsen burner flame and observe the colour change

dark red - Ca2+
green - Ba2+
red - Sr2+

24
Q

testing for ammonium compounds (litmus paper)

A
  1. add NaOH
  2. heat

results - ammonium gas

  1. use damp litmus paper and ammonia will dissolve (blue)
25
Q

testing for hydroxides (litmus paper)

A
  1. add NaOH
  2. heat

results- turns red litmus paper blue

only shows that it’s an alkali not what specific hydroxide is present

26
Q

testing for carbonates (HCl)

A
  1. HCl reacts with carbonates to form CO2 gas
  2. limewater will turn it cloudy
27
Q

testing for sulphates

A
  1. add HCl to remove carbonates
  2. add BaCl

results- an insoluble white precipitate

Ba2+ + SO42- — BaSO

28
Q

electronegativity

A

the ability for an atom to attract e- towards its covalent bond