Halogens Flashcards

1
Q

What are the halogens?

A

Highly reactive non-metals.

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2
Q

What do halogens exist as?

A

Diatomic molecules (with single covalent bonds)

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3
Q

What ion do halogens form?

A

1- ion

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4
Q

Why does the atomic radius of group 7 elements increase down the group?

A

Additional electron shells

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5
Q

How/why does electronegativity vary down group 7?

A

It decreases- atomic radius and electron shielding increases so electrons in the outer shells are less attracted to the nucleus.

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6
Q

What type of molecule are group 7 elements and what intermolecular forces do they experience?

A

Simple covalent molecules- weak london forces

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7
Q

How does the strength of the london forces vary down group 2?

A

It increases as the relative atomic mass of the molecules increases

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8
Q

How do the melting and boiling points vary down group 7?

A

Melting points and boiling points increase down the group.

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9
Q

What state are the first 4 halogens at room temperature?

A

F2 = pale yellow gas
Cl2 = pale green gas
Br2 = red/brown liquid
I2 = dark grey solid

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10
Q

Why does reactivity down group 7 decrease?

A

As atomic radius increases, the nuclear attraction is weakened by additional shielding, so it is harder to attract the outer electron it needs.

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11
Q

What kind of agents are the halogens?

A

Oxidising agents - they accept electrons from species being oxidised

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12
Q

How does their oxidising power vary down the group?

A

It decreases - greater shielding and greater atomic radius.

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13
Q

How does their oxidising power vary down the group?

A

It decreases - greater shielding and greater atomic radius.

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14
Q

What kind of agents are halide ions?

A

They are good reducing agents.

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15
Q

Why does the halide ions reducing power increase down the group?

A

Electrons are easier to lose from the larger jobs since there is larger shielding and a larger atomic radius so there is a weaker attraction between the nucleus and outer electrons.

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16
Q

What is formed when NaF and sulfuric acid react?

A

NaHSO4 + HF
(Sodium bisulphate)
HF as misty fume

17
Q

What halogen can disproportionate?

A

Chlorine

18
Q

What is the equation for the disproportionation of chlorine?

A

Cl2 + H2O —> ClO- + Cl - + 2H+

19
Q

What is the disproportionation of chlorine used for?

A

Water treatment where chlorine is used in small quantities to kill bacteria

20
Q

What is the risk of chlorine disproportionation?

A

Chlorine can be toxic

21
Q

What is the equation for the reaction of sodium hydroxide and chlorine? (Production of bleach)

A

NaOH + Cl2 —> NaCl + NaClO + H2O

22
Q

What colour precipitate are all metal
Chlorides?

A

White

23
Q

What do hydrogen halides form when reacted with ammonia gas?

A

Ammonium salts ( in an acid-base reaction)

24
Q

What do hydrogen halides form when reacted with water?

A

Dilute acids.

25
Q

In solution, what ions are formed when hydrogen halides react with water?
(Acids dissociate)

A

Hydroxonium ion (H3O+) and a halide ion
(Acidic solution)