HALOALKANES AND HALOARENES Flashcards

1
Q

WHICH OF FOLLOWING COMPOUND GIVES YELLOW PPT WITH AGNO3 SOLU
1]KIO3
2]CHI3
3]KI
4]CH2I2

A

KI

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2
Q

WHAT IS FORMED BY RXN OF ETHYL BROMIDE WITH LEAD SODIUM ALLOY

A

TETRAETHYL LEAD

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3
Q

CH3BR+OH-→CH3OH +BR

A

NUCLEOPHILLIC SUBSUTION

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4
Q

ALKY IODIDES ARE OFTEN PREPARED BY THE RXN OF ALKYL CHLORIDES /BROMINES WITH NAI IN DRY ACETONE THIS RXN IS CALLED

A

FINKELSTAIN RXN

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5
Q

IN ARYL HALIDE THE CARBON LINKED TO HALOGEN ATOM IS

A

SP2 HYBRIDIZED

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6
Q

IN SN1 RXN IN FIRST STEP FORMED

A

CARBOCATION

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7
Q

CHOLORBENZENE REACTS WITH CHLORAL AND CONC H2SO4 TO FORM

A

DDT

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8
Q

THE FOLLOWING COMPOUND REACTS WITH SILVER POWDER TO FORM ACETYLENE

A

CHI3

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9
Q

PYRENE IS USED WITH ANY ONE OF FOLLOWING FOR EXTINGUSIED FIRE

A

CCL4

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10
Q

WHICH OF FOLLOWING COMPOUND IS KNOWN BY THE NAME FREON

A

CCL2F2

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11
Q

ON HEATING ETHYL IODIDE WITH ALCHOLIC KOH THE PRODUCT FORMED IS

A

ETHYLENE

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12
Q

ON HEATING C2H5OH WITH IODINE AND A BASE THE PRODUCT FORMED IS

A

CHI3

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13
Q

WHC=ICH OF THE CHEMICAL FORMULA IS OF CHLOROPICRIN

A

C(NO2)CL3

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14
Q

ORDER OF POLARITY OF CH3I,CH3BR,CH3CL MOLECULES

A

CH3CL>CH3BR>CH3I

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15
Q

CORRECT ORDER OF REACTIVITY OF ALKYL HALIDES IS

A

I>BR>CL

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16
Q

WHAT IS FORMED ON HEATING IODOFORM WITH SILVER POWDER

A

ACETYLENE

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17
Q

RASCHING METHOD IS USED FOR

A

CHLOROBENZENE

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18
Q

THE FORMULA OF THE HARMFUL PRODUCT FORMED ON KEEPING CHLOROFORM OPEN IS —-

A

POSEGEN COCL2

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19
Q

GENERAL FORMULA OF ALKYL HALIDE

A

CnH2n+1X

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20
Q

ON HEATING AROMATIC PRIMARY AMINE WITH CHLOROFORM AND ALCHOLIC CAUSTIC POTASH A BAD SMELLING GAS —- IS FORMED

A

PHENYL ISOCYANIDE

21
Q

BHC IS AN INSECTICIDE WHOSE COMMERICAL NAME IS

A

GAMMAXENE OR LINDANE

22
Q

CHLORETONE IS A HIGH GRADE –

A

HYPNOTIC MEDICINE

23
Q

SN1 RXN OCCUR IN —-STEPS

A

2

24
Q

IN HALOARENE SUBSITUTION RXNS ARE MAINLY

A

ELECTROPHILIC

25
Q

FORMULA OF REFRIGERENT FREON

A

CCL2F2

26
Q

CARBON TETRACHLORIDE IS INSOLUBLE IN WATER

A

TRUE

27
Q

CHLOROFORM IS FORMED IN COLOURED BOTTLES

A

FALSE

28
Q

IODOFORM IS USED AS AN ANTISEPECTIC

A

TURE

29
Q

BY THE RXN OF BLECHING POWDER AND ACETONE CHLOROBENZENE ARE FORMED

A

FALSE

30
Q

CH3OH CANOT BE PREPARED BY CHLOROFORM

A

TRUE

31
Q

HEXACHLORO

A

GAMMAHEXENE

32
Q

DICHLORO - DIFLUORO METHANE

A

FREON 12

33
Q

CHLORETONE

A

HYPNOTIC

34
Q

CARBONYL CHLORIDE

A

PHOSGENE GAS

35
Q

WESTRON

A

SOLVENT

36
Q

TETRA CHLOROMETHANE

A

PYRENE

37
Q

ON REACTING BENZENE WITH METHYL CHLORIDE IN PRESENCE OF ALCL3 TOLUENE IS FORMED WHAT IS NAME OF RXN

A

FRIDAL CRAFT RXN

38
Q

ALKYL HALIDES IS POLAR IN NATURE STILL IT IS INSOLUBLE IN WATER

A

DUE TO INABILITY TO FORM HYDRGEN BOND

39
Q

ON HEATING ALKYL HALIDE WITH SODIUM METAL PRODUCT FORMED IS

A

ALKANE

40
Q

ON HEATING BENZENE DIAZONIUM SALT WITH CUPROUS HALIDE AND ITS CORRESPONDING ACID HALOARENE IS FORMED WRITE NAME OF RXN

A

SANDMEYAR RXN

41
Q

ON HEATING IDODBENZENE WITH COPPER POWDER AT200*C PRODUCT OBTAINED IS

A

DIPHENYL

42
Q

WHAT IS FORMED ON TREATING BENZENE WITH CL2 IN THE PRESENCE OF SUNLIGHT

A

BHC BENZENE HEXA CHLORIDE

43
Q

WRITE CHEMICAL NAME OF DDT

A

DICHLORODIPHENYLTRICHLORETHANE

44
Q
A
45
Q
A
46
Q

WHY IS SULPHURIC ACID NOT USED DURING RXN OF ALCHOLS WITH HI??

A

H2SO4 IS AN OXIDISING AGENT IT OXIDIES HI PRODUCE DURING RXN TO I2 AND THUS PREVENT RXN BETWEEN ALCHOL AND AN ALKYL IODIDE

46
Q
A
47
Q
A