Coordination Compounds Flashcards
THE CORRECT STRUCTURAL FORMULA OF ZEISE’S SALT IS
K[PtCl3 (C2H4)]
AgCl IS SOLUBLE IN AQUEOUS SOLN DUE TO FORMATION OF
AgCl is soluble in ammonia because it form complexes [Ag(NH3)2]Cl. The formation of the complex [Ag(NH3)2]+ ion makes it behave like ionic therefore making it soluble.
WHAT GIVES A WHITE PRECIPITATE IN AQUEOUS SOLN. IN SILVER NITRATE
Pt(NH3)2]Cl2
CORRECT NOMENCLATURE OF Fe2[Fe(CN)6]2 IS
iron(III) hexacyanoferrate(II)
IN WHICH OF THE FOLLOWING COMPOUNDS OXIDATION STATE OF METAL IS ZERO:
(a) [Pt(NH3)2Cl2]
(b) [Cr(CO)6]
(c) [Cr(NH3)3Cl3]
(d) [Cr(CN)2Cl2].
[Cr(CO)6]
EXAMPLE OF dsp2 HYBRIDIZATION IS
[Ni(CN)4]2− complex ion
dsp2 hybridisation gives complexes in which central atom have a coordination number of 4.
WHICH OF THE FOLLOWING COMPLEX IS USED AS AN ANTI CANCER AGENT
cis−[PtCl2(NH3)2]
OXIDATION STATE OF Fe IN [Fe(CO)2] COMPLEX IS
ZERO
In the complex Fe(CO)5, take the oxidation number ofFe be x . Carbonyl is a neutral ligand which doesn’t have any charge. So the oxidation number of Fe would be:- = x-0×5 = 0= 0 Hence, the oxidation number of iron in this complex is 0.
GRIGNARD REAGENT IS
Organometallic compound
THE OXIDATION STATE OF Fe IN K2[Fe(CN)4] IS
+4
MOHR’S SALT IS
DOUBLE SALT
THE FORMULA OF NITROPRUSSIDE IS
Na2[Fe(CN)5NO]
WHICH OF THE FOLLOWING IS NOT AN ORGANOMETALLIC COMPOUND
C2H5MgBr
(C2H5)4−Pb
C2H5ONa
(CH3)4Al
(C2H5)4−Pb
(CONFIRM THIS ANS FROM BOOK MCQS ONCE)
ZIEGLAR NATTA CATALYST IS
(A) K[PtCl3(C2H4)]
(B) (Ph3P)3RhCl
(C) Al2(C2H5)6 + TiCl4
(D) [Fe(C5H5)2]
Al2(C2H5)6 + TiCl4
THE I.U.P.A.C NAME OF [Ni(CO)4] IS
Tetracarbonylnickel(0)
