Haber Process Flashcards

1
Q

haber process

A

produces ammonia from nitrogen and hydrogen

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2
Q

haber process equation

A

N2 (g) +3H2 (g) ⇌ 2NH3 (g)

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3
Q

how is nitrogen obtained?

A

obtained easily from air - 78% nitrogen

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4
Q

how is hydrogen obtained?

A

from hydrocarbons

from sources such as natural gas or crude oil

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5
Q

What conditions are ammonia made in?

A

pressure of 200 atm
temperature of 450°C
presence of an iron catalyst

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6
Q

pressure

A

in the balanced equation for Haber process there are 4 mol of gas on the left and 2 mol of gas on the right
higher pressure favours the forward reaction - yield of ammonia increases
hazardous and expensive to choose very high pressure - hence 200 atmosphere operating pressure

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7
Q

temperature

A

forward reaction is exothermic
backward reaction is endothermic
if temperature is increased equilibrium position will move to the left - equilibrium yield of ammonia decreases
yield of ammonia would be greater at lower temperature

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8
Q

lower temperature means…

A

lower rate of reaction

so in industry temperature is increased anyway to get a much faster rate of reaction

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9
Q

what is ammonia formed as?

A

gas

but as it cools in the condenser it liquefies and is removed

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10
Q

what happens to unreacted hydrogen and nitrogen?

A

recycled

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11
Q

iron catalyst

A

increases rate of reaction
this gets it to the equilibrium proportions more quickly
catalyst does NOT affect position of equilibrium (% yield)

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12
Q

why is the iron catalyst important in the Haber process?

A

without the catalyst - temperature would have to be raised even further to get a quick enough reaction
that would reduce the % yield even further

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