Haber Process Flashcards
haber process
produces ammonia from nitrogen and hydrogen
haber process equation
N2 (g) +3H2 (g) ⇌ 2NH3 (g)
how is nitrogen obtained?
obtained easily from air - 78% nitrogen
how is hydrogen obtained?
from hydrocarbons
from sources such as natural gas or crude oil
What conditions are ammonia made in?
pressure of 200 atm
temperature of 450°C
presence of an iron catalyst
pressure
in the balanced equation for Haber process there are 4 mol of gas on the left and 2 mol of gas on the right
higher pressure favours the forward reaction - yield of ammonia increases
hazardous and expensive to choose very high pressure - hence 200 atmosphere operating pressure
temperature
forward reaction is exothermic
backward reaction is endothermic
if temperature is increased equilibrium position will move to the left - equilibrium yield of ammonia decreases
yield of ammonia would be greater at lower temperature
lower temperature means…
lower rate of reaction
so in industry temperature is increased anyway to get a much faster rate of reaction
what is ammonia formed as?
gas
but as it cools in the condenser it liquefies and is removed
what happens to unreacted hydrogen and nitrogen?
recycled
iron catalyst
increases rate of reaction
this gets it to the equilibrium proportions more quickly
catalyst does NOT affect position of equilibrium (% yield)
why is the iron catalyst important in the Haber process?
without the catalyst - temperature would have to be raised even further to get a quick enough reaction
that would reduce the % yield even further