gypsum Flashcards
gypsum
Gypsum is a mineral found in nature. It has been used to make dental cast since 1756. It is mined as a solid mass.
Chemical Composition of Gypsum:
Chemical Composition of Gypsum:
Ca SO4 * 2 H2O – Calcium Sulfate Dihydrate
plaster dental and die stone chemical comp
Ca SO4 * 1/2 H2O (Heat to 115°C in open vat) : Plaster of Paris (β Hemihydrate)
Ca SO4 * 1/2 H2O (Heat to 130° - 200°C + increase Pressure) Dental Stone (α Hemihydrate)
Ca SO4 * 1/2 H2O (Heat to 130° - 200°C + increase Additional Pressure) Die Stone
β Hemihydrate – Plaster of Paris
β Hemihydrate – Plaster of Paris
• “Sponginess appearance”
• Irregular shaped, porous
• Uses: Study Models (Diagnostic Casts)
α Hemihydrate – Stone
α Hemihydrate – Stone
• Crystals are denser and have a “prismatic shape”
• Uses: Working Casts (Master Casts)
Die Stone
Die Stone
• More regular shaped particles with better packing ability
• Uses: Makes dies on which to wax patterns
how do plaster and stone differ
• Plaster and stone are chemically identical but physically distinct forms of the compound calcium sulfate
• Two factors contribute to the strength and abrasion resistance of the final product:
• Two factors contribute to the strength and abrasion resistance of the final product:
- Shape of the particles
- Porosity
which is weaker , plater or stone and why ?
• Plaster particles are both porous and irregular, requiring more water to mix. The resulting product has more air space because of less densely packed particles, making plaster considerably weaker than the less porous and more more densely packed stone
setting expansion
• Setting expansion is a result of the growth of crystals as they join
setting expansion of plaster and stone
• Plaster has the greatest amount of expansion at .30% and high-strength stones the lowest at .10%
types of gypsum : 5
type 1: impression plaster
- model plaster
- dental stone
- dental stone : die stone
- high strenght/ hish expansion stone
impression plaster
rarely used
mouth must me edentulous
model plaster
type 2
W/P =.45
durable but still weak compared to stone
dental stone type 3
ideal for full or partial denture and ortho models
1/p ration.30
2,5 stronger than plaster
dental stone type 4
a. Referred to as Die Stone, capable of fabricating wax patterns
b. Hard, abrasive-resistant surface
c. Pink or Green in color
d. W/P ratio = .23
e. 2 times stronger than Type III stone
5) High-Strength, High-Expansion Dental Stone (Type V)
5) High-Strength, High-Expansion Dental Stone (Type V)
a. Recent addition – was developed in response to the need for even higher-strength and high-expansion dental stones
b. W/P ratio = .20
c. Blue or Green in color
d. Most costly of all gypsum products
initial vs final setting time
Initial Setting Time
When a mix can resist penetration by a Gilmore needle, which has a tip 2.12 mm in diameter and weighs 113.4 g. 7 to 9 minutes from the beginning of the mix
Final Setting Time
A heavier Gilmore needle weighing 453.6 g with a tip 1.06 mm in diameter leaves barely a mark. 45 minutes to 1 hour before separating the cast from the impressio
accelerators
• Accelerators
a. Potassium Sulfate (K2SO4)
b. Set gypsum particles obtained from slurry water (CaSO4)
how do The dehydrate crystals in the slurry water accelerate the chemical reaction?
• The dehydrate crystals in the slurry water accelerate the chemical reaction by acting as established sites for crystallization
retarders
• Retarders a. Blood (organic substance) b. Saliva (organic substance) c. Alginate sodium phosphte
inorganic salts role
a. Accelerators at low concentrations
b. Retarders at high concentrations
borax?
inorganic salt
b. Retarders at high concentrations (Example: Borax)
when us Decreasing the amount of water in a mixture recommended?
Decreasing the amount of water is only recommended when the mixture is being used to make a base to secure models on an articulator
increasing/decreasing temp of water will have what effect ?
- Increase in temp of water to 100° F will accelerate the set
- Above 100° F will have a retard effect
- 212° F, no reaction takes place