Group 7 Flashcards

1
Q

Trend in volatility?

A

Volatility decreases down the group

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2
Q

Trend in bond strength?

A

Decrease down the group

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3
Q

What forces are found in diatomic halogens?

A

Van der Waals

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4
Q

Trend in Van der Waals forces?

A

Increases down the group

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5
Q

Trend in Mp and Bp?

A

Increases down the group

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6
Q

The bigger the molecule the bigger the van der waals forces. Why?

A

Due to the effect of instantaneous dipole induced dipole forces which are stronger due to more electrons in the halogen atoms.

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7
Q

Are halogens oxidizing or reducing agents?

A

Oxidizing

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8
Q

Trend in oxidizing power?

A

Oxidizing power decreases down the group. Ability to lose electrons decreases down the group. Reactivity decreases down the group.

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9
Q

Trend in electronegativity?

A

Decreases down the group (ability to attract electrons to itself)

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10
Q

Trend in ability to accept electrons?

A

Decreases down the group

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11
Q

Trend in reactivity with hydrogen down the group?

A

Less vigorous down the group
(H²+X²=HX)

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12
Q

What is thermal stability?

A

How well a substance can resist thermal decomposition

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13
Q

Trend in thermal stability?

A

Decreases down the group

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14
Q

Explain the trend in thermal stability?

A

Decreases down the group due to bond energies. Bonds get longer and weaker down the group due to increased atomic radius. Less energy is required to break them.

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15
Q

Trend in reducing power of halide ions?

A

Reducing power increases down the group. The ability to donate electrons increases down the group.

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16
Q

Why is it easier to oxidize HX going down the group?

A

Going down the group they become stronger reducing agents

17
Q

Disproportionation Reaction?

A

Reaction where a species is both oxidized and reduced.

18
Q

Chlorine plus cold dilute alkali?

A

NaClO (+1)
NaCl (-1)

19
Q

Chlorine plus hot alkali?

A

NaClO3 (+5)
NaCl (-1)

20
Q

Chlorine plus water?

A

HCl (-1)
HClO (+1)

21
Q

Trend in density?

A

Increases down the group