Group 2- textbook ntes Flashcards
why is group 2 called the alkaline earth metals
- their oxides and hydroxides are alkaline
as you go down the group the size of the atom
increase as shielding increases down the group
melting point
- the electrons in the sea of delocalised electrons are further away from the positive nuclei
- as a result the strength of the metallic bonds decreases going down the group
- therefore melting points of grp 2 decrease slightly going down the group
how does Mg react with cold water and steam
- very slow with cold water to form metal hydroxide (aq) and hydrogen
- rapidly with steam to form an alkaline oxide and hydrogen
describe solubility of Mg Ca St Ba
almost insoluble
soluble
more soluble
dissolves to produce a strongly alkaline solution
solubility of sulphates
decreases down the group
Ba- is insoluble
what can the insolubility of barium be of use to
simple test for sulphate ions in solution
- solution first acidified with nitric or hydrochloric acid
- barium chloride solution then added
- if a sulphate is present a white precipitate of barium sulphate forms
how do group 7 non-metals exist
diatomic molecules
what colour is F at room temp
pale yellow gas
what colour is Cl at room temp
green gas
what colour is Br at room temp
red-brown liquid
what colour is I at room temp
black solid
down the group grp 7 (physical properties)
darker and denser down the group
what is electronegativity
ability of an atom to attract electrons, or electron density towards itself within a covalent bond
what does electronegativity depend on
- attraction between the nucleus and bonding electrons in the outer shell
electronegativity down the group
decreases going down the group
explain why electronegativity decreases going down the group
the shared electrons in the bond get further away from the nucleus as the atoms get larger going down the group
- this makes the shared electrons further from the halogen nucleus and increases the shielding by more inner shells of electrons
melting and boiling points in grp 7
increase going down the group
explain why melting and boiling points increase going down the group
- larger atoms have more electrons
- this makes the London forces between the molecules stronger
- this means more energy is required to break the intermolecular forces between them