group 2 - alkaline earth metals Flashcards

trends in physical + chemical properties

1
Q

which block are group 2 elements found in?

A

s-block

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2
Q

the trend in atomic radius across a period

A
  • atomic radius decreases
  • more protons
  • similar shielding
  • stronger nuclear attraction to outer electron
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3
Q

the trend in atomic radius down a group

A
  • atomic radius increases
  • more electron shells
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4
Q

the trend in ionisation energy down group 2

A
  • ionisation energy decreases
  • no. of electron shells increases
  • more shielding
  • weaker nuclear attr. to electron in outer shell
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5
Q

the trend in reactivity down group 2

A
  • reactivity increases
  • lower 1st/2nd ionisation energies
  • loses electrons & forms +ve ions quicker
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6
Q

the trend in melting point down group 2

A
  • melting point decreases
  • weaker metallic bonding down group
  • as metal ions are bigger
  • lower nuclear attr.
  • less energy needed to remove outer electron
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7
Q

group 2 bonding

A
  • metallic bonds
  • giant lattice of cations
  • strong electrostatic forces of attr. between the cations and delocalised electrons
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8
Q

what type of cations do group 2 metals form?

A

eg. Mg2+

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9
Q

product of metal + cold water โ€“>

(all group 2 elements form this apart from Mg)

A

metal hydroxide + hydrogen

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10
Q

product of metal + steam โ€“>

A

metal oxide + hydrogen

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11
Q

appearance of all oxides

A

white powders

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12
Q

reaction of group 2 elements with water

A

react more vigorously with water as you go down the group

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13
Q

which group 2 element doesnโ€™t react with cold water?

A

Mg โ€“> only reacts with steam

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14
Q

test for Mg

A
  • burns with bright flame
  • lit splint goes out with squeak and pop
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15
Q

trend in group 2 hydroxide solubilities down the group

A

increases in solubility

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16
Q

Ba(OH)2

A
  • toxic
  • fatal consequences if ingested
17
Q

trend in group 2 sulfate solubilities down the group

A

decreases in solubility

18
Q

BaSO4

A
  • insoluble
  • so body wonโ€™t absorb it
  • barium meals can be used for patients who req. a gastric study
19
Q

ionic formula to form group 2 sulfate

A

eg. Ca2+(aq) + SO4^2-(aq) โ€“> CaSO4 (s)

20
Q

chemical test to test for presence of sulfates

A
  • add acidified barium chloride
  • if sulfate ions are present, a dense, white precipitate of barium sulfate is formed
    (must use HCL or HNO3 instead of H2SO4 to prevent false detection of sulfite ions)
21
Q

chemical test to test for presence of barium

A
  • add H2SO4 to solution which may contain barium
  • if barium present, a dense, white precipitate is formed
22
Q

the extraction of titanium

A

-displacement reaction
-magnesium used
- TiCl4 + 2Mg โ€”> 2MgCl2 + Ti

23
Q

flue gas desulfurisation

A

-neutralisation reaction
-between calcium oxide and sulfur dioxide