Glass Ionomer Cements Flashcards
What is a glass ionomer
Group of materials that use silicate glass powder in an aqueous solution of poly acrylic acid
What is a cement
A substance that hardens to act as a base, liner, filling material or adhesive. To bind structures to each other or the tooth surface
What are the most important characteristics of a restorative material?
Aesthetics
Biocompatibility
Strength
Speed
Patient and case related factors to think about with restorability?
Patient compliance
Aesthetics
Caries risk
Aesthetic concern
Why would you treat a patient with GIC?
High caries risk
Temporary solution needed
Less cooperative patients
What are its constituents?
Constituents-
Liquid-
Poly acrylic acid
Water- hydrates the hydrogel
Itaconic acid- increases working time
Modifiers
Itacontic acid- promotes reactivity
Maelic acid- causes cement to lose moisture sensitivity faster
Classifications- based on its use?
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Class I luting cements
II restorative material
III bases and liners
IV pits and fissure sealants
V orthodontic luting
VI Core build up
VII command set (high flouride)
VIII ART
IX paediatric
Advantages of GIC?
Ability to bond to enamel and dentine
Moisture tolerant
Tooth coloured
Flouride leaching
Good biocompatibility
Chemical bond
Coefficient of thermal expansion is similar to dentine
Disadvantages of GIC?
Poor wear resistance
Vulnerability to acid erosion
Low fracture toughness- poor in high occlusal load areas
Low flexural strength
Finishing and polishing times
Types of GIC?
Conventional GIC
Conventional Reinforced GIC
Resin modified GIC (light activated, combines properties of a resin material and GIC)
Talk about the constituents of GIC
Glass powder- replacing calcium with strontium or lanthanum increases radiopacity, reduced particle size improves the physical properties, flouride improves the handling properties- slows the setting time to increase the working time
Tartaric acid
Water- essential component
PAA- increased molecular weight or concentration of PAA molecules improves the physical properties
Describe the setting reaction of GIC
Acid base reaction- PAA plus water—-hydrogen ion release
Hydrogen ions cause aluminosilicate glass to release calcium and aluminium ions - dissolution phase- which replace the H+ ions in the acid
This causes the PAA matrix (made of 2(FAS-core) to release calcium ions- this is the hardening phase, and silicone hydrogel- that is the gelation phase, rising pH, important to isolate
What is reinforced GIC
Modified conventional GIC
Compare reinforced GIC to conventional GIC and what effect does this have clinically?
Improved compressive and flexural strength, hardness, wear resistance and solubility.
Improved outcomes in load bearing areas
Improved clinical handling
Improved radiopacity
Examples of reinforced GIC
Chemflex and Fuji IX
Indications for Fuji IX (a type of reinforced GIC)
Deciduous teeth
Adult-
Restorations- class I, II and V restorations
As a core build up
Base/liner- sandwich technique
What is then definition of a resin modified GIC?
Materials set by an acid base reaction in an aqueous environment in the presence of a photoplymerisation reaction
What are the key chemical reactions with reinforced GIC?
HEMA goes to camphourquinone which goes to poly-HEMA
HEMA (2-hydroxyethyl-methacrylate)
What is reinforced GIC in relation to conventional GIC
Conventional GIC plus resins and photoinitiators goes to resin modified GIC
What is the setting reaction for RMGIC? N
Acid base reaction : Polyalkenoic acid in the presence of HEMA plus water releases hydrogen ions
Hydrogen ions cause aluminosilicate glass in the presence of camphorquinone to release calcium and aluminium ions
The aluminosilicate glass is activated by light to cause the PAA matrix (2(FAS-core-polyHEMA) to release calcium ions (hardening phase) and silicone hydrogel
What are the benefits/ importance of the setting reaction for Resin modified GIC?
Immediate hardening can cause
3 setting phases: ionic cross linking, photopolymerisation (light), free radical cure (dark)
What are some examples of RMGIC?
Vitremer and Fuji II LC
Indications of Fuji II LC?
Deciduous teeth
Adult-
Restorations- class III and class V (cervical erosion, abractions, root surface caries)
Core build up
As a base/liner- sandwich technique
Caution with RMGIC?
Increased risk of allergy due to HEMA
Hydrophilic- if it absorbs too much water it will expand
Potential for disolcouration