Amalgum Flashcards
What is amalgam
An alloy containing mercury
What is an alloy?
A mixture of 2 or more metals in which the primary constituent is a metal
What are the constituents of amalgam?
Mercury
Silver
Tin
Copper
Trace elements (zinc, silver, palladium)
What are the types of amalgam and what is conventional amalgam?
Several types of amalgam alloy. They all contain tin, most have copper and some have zinc
Conventional amalgam is 67-74 percent silver, 25-28 percent tin, 2 percent zinc, 3 percent mercury
What does silver do?
Increases strength and hardness
What does tin do?
Increases plasticity- aids amalgamation process due to its high affinity for mercury
What does copper do?
Reduces plasticity
Increases strength and hardness
What does tin do?
Not needed by prevents oxidation during manufacture
What does mercury do?
Activates the reaction- the only metal that can bind to metals in such away that the material can be easily manipulated into the cavity
Palladium
Reduces corrosion and increases lustre
Indium
Reduces creep
Classification of amalgam
Copper content- low copper content 0-6 percent high copper content > 6-13 percent
Zinc content- zinc containing more than 0.01-2 percent, non-zinc <0.01 percent
Shape of alloy particles- spherical, lathe cut or admixed
What are the key properties of amalgam
Strength-
Corrosion
Creep
Thermal properties
Strength
Compressive strength>over tensile strength: note amalgam is weak in thin sections
Affected by: type of alloy, shape and size of particle, amount of mercury and manipulation of the mix
Gamma phase 2 is the weakest so you want to limit this phase, compress into cavity so that unreacted core of particles are packed closely together and mercury rich layer is brought to the surface and removed.
Corrosion
Heterogenous, multiphase structure
May eventually form a seal
Can be accelerated in a ‘Galvanic cell’
Creep
The flow is caused by loads acting over long periods
Leads to unsupported enamel over the cavity margin, further weakened by corrosion, leads to ditching of margins