Glass Industry Flashcards
Definition of glass, physically
a rigid, undercooled liquid having no definite melting point and a sufficiently high viscosity (greater than 1012 Pa.s) to prevent crystallization.
Definition of glass, chemically
combination of nonvolatile inorganic oxides formed by the decomposition and fusion of alkali and alkaline earth compounds, sand, and other glass constituents, resulting in a product with a random atomic structure.
Glass has many uses because of its
transparency, high resistance to chemical attack, effectiveness as an electrical insulator, and ability to contain a vacuum.
Ancient Phoenician merchants discovered glass while
cooking a metal in a vessel place accidentally upon a mass of trona at the seashore
were making sham jewels of glass which were often of fine workmanship and marked beauty.
As early as 6000 or 5000 B.C the Egyptians
invented the hand-blown window glass cylinder.
A monk from the twelfth century
Glass work in the United States were founded in
1608 at Jamestown, Virginia, and in 1639 at Salem, Massachusetts
Major ingredients of glass
Sand
Lime
Soda ash
The most important factors in making glass are
viscosity of molten oxides and the relation between this viscosity and composition
commercial glasses fall into several classes
- Fused silica (vitreous silica)
- Alkali silicates
- Soda-lime glass
- Lead glass
- Borosilicate glass
- Special glasses
- Glass fibers
Made by the high-temperature pyrolysis of silicon tetrachloride or by fusion of quartz or pure sand.
Fused silica
is widely consumed as an adhesive for paper in the manufacture of corrugated paper boxes.
Silicates of soda solution also known as water (soluble) glass
• Sand and soda ash are simply melted together, and the products designated sodium silicates
• It aided the glass technologist in understanding the behavior of more complicated systems
Alkali silicates
• constitutes 95% of all glass manufactured
• Used for containers of all kinds, flat glass, automobile, and other windows, tumblers, and tableware.
Soda-lime glass
• obtained by substituting lead oxide for calcium oxide in the glass melt
• Because of their high index of refraction and dispersion, these glasses are extremely useful in optical work
Lead glass
• usually contains about 10 to 20% B2O3, 80 to 87% Silica and less than 10% Na2O.
• has a low expansion coefficient, superior resistance to shock, excellent chemical stability, and high electrical resistance.
Borosilicate glass
the laboratory glassware made from borosilicate glass is sold under the tradename
Pyrex
Colored and coated, opal, translucent, safety, optical, photochromic glasses, and glass ceramics are ______. All of these have varying compositions depending upon the final product desired
Special glasses
• produced from special glass compositions that are resistant to weather conditions.
• The very large surface area of the fibers makes them vulnerable to attack by moisture in the air.
• This glass is low in silica, about 55%, and low in alkali
Glass fibers
Raw materials of glass
- Sand
- Soda
- Feldspar
- Borax
- Salt cake
- Cullet
- Refractory blocks
- Decolorizer