Glass, ceramics, light sources Flashcards
What is glass ?
*An amorphous solid material – in between the crystalline and the liquid state
*Its molecules are arranged in irregular pattern
Pros of glass
o Visible transmittance
o Optically transparent
o Weather and rust resistant
o Dustproof and waterproof
o Safe packaging material
o Insulator of eletricity
o Colour availability
o Recyclable
o UV stable
Cons of glass
o Brittleness
o Heat transparency
o Fragile
Division of raw materials
Major and Minor
Major raw materials
Quartz/silica sand
Soda ash
Limestone
Minor raw materials
Dolomite
Crushed/recycled glass (cullet)
Boric acid, lead oxide, sodium oxide (to get coloured glass)
History of glass
o The first manufactured glass material appeared 6000 years ago
o 1st Century B.C. – glass blowing begins (blow pipe was developed)
o By the 16th Century – glass was made all over Europe
Glass processing steps
Fusion of raw materials
Working with molten glass
Annealing
Finishing
Fusion of raw materials
- The raw materials are weighed and mixed together to form the BATCH. Later broken glass is added to lower the temperature. The batch is melted in a furnace.
- The furnaces are usually electrical, gas-fired, or oil-fired. The temperature varies from 1500°C to 2800°C according to the type of product.
Working with molten glass
- Blowing (automatic blowing – bottles, lamp bulbs, traditional hand blowing)
- Casting (large pieces of glass – mirror)
- Drawing (Windows – thin sheets of glass)
- Pressing (glass bricks, lenses)
- Rolling (wired and plate glass)
Annealing
- Annealing of glass is a process of slowly cooling down hot glass objects after they have been formed (glass will break when cooled suddenly)
- In glass manufacturing, a special type of furnace, a Lehr is used for this process
- Glassware moves through the oven’s zones on a conveyor belt
- After annealing the glass can be cut, drilled, sized and polished for use
Finishing
- Cleaning
- Griding
- Polishing
- Etching
- Engraving
- Sandblasting
- Cutting
- Painting
How do we colour glass
- Red colored glass can be obtained by adding selenium sulfide
- Blue glass can be obtained by adding copper oxide
- Milky glass can be obtained by adding alumina or phosphate
Types of glass
- According to the melting point
- According to chemical composition
- Decorative and technical glass
- According to the melting point
o Soda glass – soft glass - melting temperature of batch is 1300°C, bottles, windows
o Quartz glass – hard glass - melting temperature of batch is 1500°C, wine glasses, electrical bulbs
o Pyrex glass - melting temperature of batch is 1700°C, baking Jena dish, laboratory glass ware
- According to chemical composition
o Silica glass
o Soda-lime glass – bottles
o Flint glass (lead glass) – optical lenses
o Borosilicate glass – glassware in kitchens and laboratories
o Alumo-silicate glass – screen of smartphones
- Decorative glass
o Lead crystal glass – it sparkles, expensive glass ware
Technical glass
Chemical – glassware in laboratories
Optical – cameras, lenses, glasses
Building – windows
Safety – car glass, wired glass
Glass fibers – surfboardsk, helmets, canoe
Future of glass
- Functional integration of glass that can become an ideal substrate for OLED lighting, touch screens, etc.
- Bioactive glass – include the original bioactive glass, bioglass, implant materials in the human body to repair and replace diseased or damaged bones
- Smartphones – bendable glass, scratch resistance
- Special coatings for buildings: Smart mirrors and highly insulating glass windows
Testing of glass
- Impact testing
- Thermal schock resistance
- Physical inspection
- Stress testing
Origins of ceramics
o Word ceramics derives from the Greek word keramos/keramikos, meaning “a potter” or “made of clay”
o One of the oldest human crafts
o The oldest ceramic object discovered is the statue of Venus
o The potter’s wheel has become a tool for creating pottery (Mesopotamia, 6000-4000 BC)
Raw materials (ceramics)
o Plastic base
o Fluxes (tavivá)
o Fillers (ostrivá)
o Colours/dyers
Plastic base
Ball clay
Stoneware clay
Kaolin
Fluxes
Silica
Feldspar
Talc
Fillers
Limestone
Other
Colours/dyers
Metal oxides