Gibbs Free Energy, Enthalpy, Entropy Flashcards

1
Q

What is kinetic energy?

A

The energy of a system’s particles in motion

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2
Q

What is potential energy?

A

The energy of a system based on its’ position

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3
Q

What is thermal energy?

A

The energy contained in a system that affects its temperature.

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4
Q

What is Gibbs Free Energy?

A

The max amt of potential energy in a system that can be released to the surroundings

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5
Q

ΔH(-)
ΔS(+)
ΔG(-)

What is the reaction spontaneity at high temp?
What is the reaction spontaneity at low temp?

A

ΔG is NEGATIVE @ ALL temperatures

Spontaneous @ ALL temperatures

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6
Q

ΔH(+)
ΔS(-)
ΔG?
Reaction spontaneity based on temperature?

A

ΔG is POSITIVE @ ALL temperatures

Nonspontaneous @ ALL temperatures

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7
Q

ΔH(-)
ΔS(-)
ΔG?
Reaction spontaneity based on temperature?

A

ΔG is NEG @ LOW temp
ΔG is POS @ HIGH temp

SPON @ LOW temp
NONSPON @ HIGH temp

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8
Q

ΔH(+)
ΔS(+)
ΔG?
Reaction spontaneity based on temperature?

A

ΔG is POS @ LOW temp
ΔG is NEG @ HIGH temp

NONSPON @ LOW temp
SPON @ HIGH temp

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9
Q

Negative ΔG?

(The reaction is…?)

A

Spontaneous reaction

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10
Q

Positive ΔG?

(The reaction is…?)

A

Nonspontaneous reaction

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11
Q

Equation for Gibbs Energy?

(H, S, and T)

A

ΔG= ΔH- TΔS(sys)

“hottas”
HΔ - TΔS

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12
Q

Second equation for Gibbs Energy?

(T, S of univ)

A

ΔG= -TΔSuniv

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13
Q

Equation for Heat capacity

A

q=CΔT

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14
Q

Equation for Specific Heat

A

q=mCsΔT

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15
Q

Equation for ΔSsurr?

A
 T (K)
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16
Q

Gas Law for moles of gas and volume of gas

A

V1/n1= V2/n2

17
Q

Gas Law for pressure of gas and volume of gas

A

P1V1=P2V2

18
Q

Gas Law for volume and temperature of a gas

Is temperature in C or K?

A

V1/T1= V2/T2

Temp is in Celcius

19
Q

Molarity Equation

A

M1V1= M2V2