General Chemistry Flashcards

1
Q

Combustion reaction

A

Hydrocarbon or alcohol reacts with O2 to form CO2 and H2O

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2
Q

Cohesion in measuring tool

A

Molecules of liquid stick to each other - forming convex meniscus

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3
Q

Adhesion in measuring tool

A

Molecules of liquid stick to glass of tool - forming a concave meniscus

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4
Q

Neutralization problems

A

n1M1V1 = n2M2V2

n - is normality. How many equivalents of H+ and OH- there are…

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5
Q

Bond strength decreases…

A

…as the difference in electronegativity increases

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6
Q

A stronger acid has…

A

Weak bond strength

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7
Q

Bond dissociation energies are always…

A

Positive

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8
Q

Half life for 1st order reaction

A

t(1/2) = 0.693/k

k - is the rate constant

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9
Q

Accuracy

A

Measurement is close to true value

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10
Q

Precision

A

Measurement is consistent

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11
Q

Good electrolytes

A

Strong acids, strong bases, ionic compounds

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12
Q

Best definition of boiling point

A

Temp when VP of liquid equals surrounding pressure

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13
Q

Volatility

A

Ability for liquid to evaporate

More volatile=weak IMF’s

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14
Q

[H+] for weak acids…

A

=sqrt(Ka x M)

**also for OH-, just with Kb

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15
Q

Reacting a hydrocarbon with oxygen produces…

A

H20 and CO2

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16
Q

0th law of thermodynamics…

A

Two systems are in equilibrium with a third…then they are all in equilibrium with each other

17
Q

Work eqn at constant pressure (isobaric)…

A

W=-P(V2-V1)

18
Q

Henry’s Law (solubility of a gas)

A

C=kP

C - cons of a gas in soln
P - partial pressure of gas above soln

19
Q

Non state functions

A

Heat and work

20
Q

Zero order reaction

A

Slope=-k

Plot is conc vs time

21
Q

1st order reaction

A

Slope=-k

Plot is ln(conc) vs time

22
Q

2nd order rxn

A

Slope = k

1/conc vs time

23
Q

Which elements react violently with pure oxygen?

A

Group 1 and 2 metals

Group 1 alkali react more violent than group 2alkaline earth metals

24
Q

Nuclear binding energy

A

Energy needed to split the nucleus

25
Q

Boyles law

A

P1V1 = P2V2

26
Q

Charles Law

A

V1/T1 = V2/T2

27
Q

Allotrope

A

Different structural forms of the same element

28
Q

Gas solubility increases when…

A

Pressure increases

Temperature decreases

29
Q

7 diatomic molecules

Never have fear of ice cold beer

A
Nitrogen
Hydrogen 
Fluorine
Oxygen
Iodine
Chlorine
Bromine
30
Q

Bond energies

A

Bonds broken - bonds formed

31
Q

Isoelectronic

A

Same amount of valence electrons

32
Q

Vacuum filtrations

A

Technique that separates particles based on charge

33
Q

Diamagnetism

A

Repels magnetic fields

34
Q

Paramagnetism

A

Attracts magnetic fields

35
Q

Atoms charge goes down

A

Reduced

36
Q

Atoms charge goes up

A

Oxidized

37
Q

Lower Rf

A

More polar

38
Q

Higher Rf

A

Less polar