GENERAL CHEMISTRY Flashcards

1
Q

Mass #

A

protons + neutrons

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2
Q

atomic #

A

of protons

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3
Q

Mass in grams on periodic table

A

average of all isotopes

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4
Q

Important Groups on periodic table

A
  1. alkali metals - basic, react with H2O (explosive), highly exothermic rxn, form strong base
  2. alkali earth metals - basic, not as reactive but still reactive to H2O, gets stronger as you move down group
  3. Noble gases- has full octet, no reactive
  4. Halogens
    * transition metals form bright colored complexes
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5
Q

what are the 4 orbitals?

A

s,p,d,f

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6
Q

Rules for orbitals

A
n = Shell#, n^2 = number of orbitals
2n^2 = max # of electron capacity
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7
Q

Exceptions to electron configuration rules

A

Copper (Cu), Silver (Ag), Gold (Au), Chromium (Cr), Molybdium (Mb)

*full or partial subshells are more stable

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8
Q

Paramagnetic

A

attracted to a magnetic field, have unpaired electrons (at least one unpaired)

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9
Q

Diamagnetic

A

has slight deflection away from magnetic field

all electrons are paired

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10
Q

n, l, ml, ms

A

n= principle quantum number - tells what shell you are in

l = azimuthal quantum # - tells the type of subshell (s,p,d,f)
s = 0, p =1, d=2, f=3

ml = magnetic quantum # - tells specific orbital

ms= spin quantum # - tells if electron is up or down spin

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11
Q

range of quantum numbers (n, l, ml, ms)

A
n = 1 to infinity
l = 0 to (n-1)
ml = -l to l
ms = -1/2 or + 1/2
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12
Q

electron is higher energy

A

farther from nucleus

electron is lower energy closer tot he nucleus

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13
Q

Nuclear force/Nuclear binding energy

A

energy that holds protons and neutrons together (overpowering electrostatic forces of +++)

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14
Q

alpha particle

A

same as helium nucleus 4/2 He

heaviest particle, not very penatrative to skin

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15
Q

Proton

A

1/1 P

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16
Q

Neutron

A

1/0 N

17
Q

Beta particle/electron

A

0/-1 B or 0/-1e

18
Q

positron

A

0/+1 B or 0/+1 e

19
Q

gamma ray

A

0/0 Y

the lightest particle, very penetrative to skin

20
Q

Stable nucleus

A
  • has even # of protons and/or neutrons
  • needs 1:1 ratio N/Z (neutrons to protons) – only up to atomic #20.
  • magic #s
21
Q

alpha decay

A

emission of 4/2 alpha

most heavy atoms under go this to get rid of mass
for atomic # >83

22
Q

beta decay

A

emission of 0/-1 e

used when N/Z is too high (need to get rid of neutrons)
n–>p to get a 1:1 ratio

23
Q

positron emission

A

emission of 0/+1 e

when N/Z too low (turning proton to neutron) to get 1:1 ratio

24
Q

Electron Capture

A

NOT emission (this is on reactant side) – nucleus pulls electron from inner core 0/-1 e

turning proton to neutron when N/Z is too low to get 1:1 ratio

25
Q

Kinetics of Nuclear decay

A

FIRST ORDER

rate is proportional to concentration and have CONSTANT half life

26
Q

Most stable nucleus

A

56/26 Fe

has highest nuclear binding energy PER NUCLEON

nucleon is a proton or neutron
*any element close to this mass# has a high nuclear binding energy per nucleon

27
Q

VSEPR Theory

A

know all molecular and electron domain geometries