General Chemistry 2 Flashcards

1
Q

The study Of energy or heat Flow that accompanies a chemical reaction and/or physical transformation

A

THERMOCHEMISTRY

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2
Q

a Form Of energy transfer between two objects as a result of their difference in temperature

A

HEAT

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3
Q

the part of the universe being studied or to which attention Is Focused

A

SYSTEM

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4
Q

include everything else in the universe

A

SURROUNDING

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5
Q

Heat is represented by this letter

A

q

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6
Q

heat flows From a system to its surroundings; - q

A

EXOTHERMIC

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7
Q

system absorbs heat From surroundings; +q

A

ENDOTHERMIC

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8
Q

a branch of thermodynamics, which deals with the interconversion of energy between two forms: heat & work

A

THERMOCHEMISTRY

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9
Q

States that energy can neither be created nor destroyed, It can only be transferred between the system and surroundings

A

LAW OF CONSERVATION OF ENERGY

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10
Q

Based on the first law of thermodynamics, the equation on the change in energy Of a system

A

E = q + w

q = heat absorbed, w = work done

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11
Q

Involves the measurement of the quantity of heat exchanged between a system and its surroundings

A

CALORIMETRY

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12
Q

measures the Flow of energy (as heat) between the system and its surroundings

A

CALORIMETRY

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13
Q

The amount of heat absorbed or released by the system is a function of its change in temperature

A

q = C∆t

q = heat (J)
∆t = change in temp. (°C)

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14
Q

Proportionality constant that shows the relationship between heat and temp. change. Also the amount of energy needed to raise the temp. of a substance by 1°C. (J/°C)

A

Heat Capacity (C)

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15
Q

Heat Capacity is equal to the product of its _____ and _____.

A

mass (m), specific heat (c)

C = mc

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16
Q

The amount of energy needed to increase the temp. of one gram of a substance by 1°C. (J/g°C). Also, it is constant for some substances.

A

Specific Heat (c)

17
Q

An insulator apparatus that contains water or liquid of known heat capacity. It determines the heat capacity of a substance.

A

Calorimeter

18
Q

The System of a Calorimeter is composed of two parts:

A

Substance and Chemical Reaction

19
Q

Heat exchange in a calorimeter is expressed as (when the calorimeter is an excellent insulator and absorbs only a negligible amount of heat)?

A

q (sys) = - q (water)

or

q (sys) = - mc∆t (water)

20
Q

A typical calorimeter used in experimentation which is usually made with a polystyrene cup that is a good insulator.

A

Coffee-Cup Calorimeter

21
Q

Parts of a Coffee-Cup Calorimeter

A

Thermometer and Stirrer

22
Q

Total Heat Transferred (absorbed or released) in a chemical reaction at constant pressure, and often referred to as Heat Content.

A

Enthalpy (H)

23
Q

A Balanced Equation that also specifies Heat Flow for the reaction.

A

Thermochemical Equations

24
Q

Expresses a quantitative relationship between the amounts of substances that react and the heat of the reaction

A

Thermochemical Equations

25
Q

In writing a Thermochemical Equation, where is the heat flow listed beside the balanced chemical equation?

A

In the right side

aA + bB —> cC ∆H = ___kJ

26
Q

___ is directly proportional to the quantity of a substance that reacts or is produced by the reaction. If the coefficients in an equation are doubled, the value of ___ is multiplied by 2.

A

∆H

27
Q

∆H that accompanies a chemical reaction; is the net energy change resulting from the breaking and formation of bonds.

A

Heat of Reaction

28
Q

The Heat of reaction can be solved using the equation:

A

∆H°rxn = Σ∆H°f (products) - Σ∆H°f (reactants)

29
Q

The change in enthalpy when the compound was formed from its elements under standard conditions.

A

Enthalpy of Formation