GenChem2 (PeriodicTable) Flashcards

1
Q

Periodic Law states that the chemical properties of the elements are dependent, in a systematic way, upon their

A

Atomic numbers

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2
Q

How many periods (rows) are there?

A

7

They represent n=1 to n=7

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3
Q

Groups represent elements that have the same electronic configuration in their _____, and the have similar chemical properties because of it

A

Valence Shell

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4
Q

The Roman numeral above each group represents the number of

A

Valence Electrons

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5
Q

A groups have ____ sublevels as their outermost orbitals

B groups have _____ sublevels as their outermost orbitals

A

s and p

d and f

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6
Q

The B elements include these groups

A

transition elements
lanthanide series
actinide series

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7
Q

This B element group has partially filled d levels

A

Transition elements

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8
Q

This B element has partially filled f sublevels

A

Lanthanide and Actinide Series

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9
Q

As one goes from left to right across a period, the electrons of the outermost shell experience INCREASING/DECREASING amount of nuclear attraction

A

As one goes from left to right across a period, the electrons of the outermost shell experience INCREASING amount of nuclear attraction
(they become closer and more tightly bound to the nucleus)

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10
Q

As one goes down a column, the outermost electrons become MORE/LESS tightly bound to the nucleus

A

As one goes down a column, the outermost electrons become LESS tightly bound to the nucleus

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11
Q

The _____ is equal to one-half the distance between the centers of two atoms of that element that are just touching each other

A

Atomic radius

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12
Q

Atomic radius ______ from right to left and ________ down a given group

A

Atomic radius decreases from right to left and increases down a given group

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13
Q

The atoms with the largest atomic radius will be located where on the periodic table?

A

Bottom of group 1

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14
Q

The energy required to completely remove an electron from a gaseous atom or ion.

A

Ionization Energy (IE) or Ionization Potential

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15
Q

Is removing an electron exothermic or endothermic?

A

Endothermic, as it requires energy.

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16
Q

The energy required to remove one valence electron from the parent atom

The energy required to remove a second valence electron from the univalent ion to form the divalent ion

A

Second Ionization energy

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17
Q

Which has a greater ionization energy, second or first ionization energy?

A

second ionization energy

IEs grow increasingly large

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18
Q

From left to right across the periodic table, ionization energy INCREASES/DECREASES

Why?

A

From left to right across the periodic table, ionization energy INCREASES

The atomic radius DECREASES

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19
Q

Moving down a group, ionization energy INCREASES/DECREASES

Why?

A

Moving down a group, ionization energy DECREASES

The atomic radius increases

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20
Q

Defined as the energy change that occurs when an electron is added to a gaseous atom, and represents the ease to with which the atom can accept an electron.

A

Electron Affinity

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21
Q

Positive electron affinity (in this text) represents energy absorption when an electron is added or energy release?

A

Energy release

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22
Q

Group IIA elements have HIGH/LOW electron affinityies

Group VIIA elements have HIGH/LOW electron affinities

A

Group IIA elements have LOW electron affinityies

Group VIIA elements have HIGH electron affinities

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23
Q

A measure of the attraction an atom has for electrons in a chemical bond

A

Electronegativity

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24
Q

Electronegativities are related to…

A

Ionization energies

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25
Q

Electrons with low ionization energies have HIGH/LOW electronegativities

Why?

A

Electrons with low ionization energies have LOW electronegativities

Their nuclei do not strongly attract electrons.

26
Q

Electrons with high ionization energies have HIGH/LOW electronegativities

Why?

A

Electrons with high ionization energies have HIGH electronegativities

The nucleus has a strong pull on the electrons

27
Q

As you move from left to right across the periodic table, electronegativity ______

As you increases the atomic number in a group, electronegativity ______

A

Increases

Decreases because of increased distance between valence shell and nucleus

28
Q

The three categories of elements in the periodic table

A

Nonmetals, Metals, Metalloids

29
Q

Category of elements that have high densities and high melting points, and are solid at room temperature

A

Metals

30
Q

Metalshave the ability to be deformed without breaking, like hammering it into different shapes. This characteristic ability of metals is called

A

Malleability

31
Q

The ability of metal to be drawn into a wire

A

Ductility

32
Q

Metals have a SMALL/LARGE atomic radius
Metals have a HIGH/LOW IE
Metals have a HIGH/LOW electronegativity

These properties are explained by

A

Metals have a LARGE atomic radius
Metals have a LOW IE
Metals have a LOW electronegativity

These properties are explained by the few electrons in the valence shell which can be easily removed.

33
Q

Metals are BAD/GOOD conductors of electricity and heat?

Why?

A

Metals are GOOD conductors of electricity and heat

The valence electrons can move freely

34
Q

Which metals are the most reactive metals?

A

Groups IA and IIA

35
Q

This category of elements is brittle in the solid state and show little or no metallic luster.

A

Nonmetals

36
Q

Nonmetals have HIGH/LOW IE
Nonmetals have HIGH/LOW electronegativit
Nonmetals are GOOD/POOR conductors of heat and electricity

A

Nonmetals have HIGH ionization energies
Nonmetals have HIGH electronegativity
Nonmetals are POOR conductors of heat and electricity (usually)

37
Q

Name the one characteristic of nonmetals that they share, otherwise they have a wide range of chemical behaviors and reactivities

A

Nonmetals share the ability to gain electrons easily

38
Q

The category of elements located along the line between the metals and nonmetals on the periodic table

A

Metalloids

39
Q

Are metalloid properties universal or diverse?

A

Their properties vary considerably

Densities, BPs, and MPs

40
Q

Metalloids have HIGH/LOW/INTERMEDIATE electronegativites and IEs

A

Intermediate between metals and nonmetals, they possess characteristics of both classes

41
Q

What does the reactivity of metalloids depend pon?

A

The element with which they are reacting

42
Q

B behaves as a nonmetal when reacting with…

B behaves as a metal when reacting with…

A

Na

F

43
Q

Name the elements classified as metalloids

A

Boron, Silicon, Germanium, Arsenic, Antimony, Tellurium

44
Q

The elements of group IA are referred to as

A

Alkali Metals

45
Q

How do alkali differ from other metals?

Why?

A

They have lower densities.

They have one loosely bound electron in the valence shell, meaning they have the largest atomic radii in a period.

46
Q

Alkali metals have ____ IEs
Alkali metals have ____ electronegativity
Alkali metals have _____ reactivity

Why?

A

Low IEs
Low electronegativity
High reactivity

They easily lose their valence electron

47
Q

What group do alkali metals react easily with? Especially…

A

Nonmetals, especially halogens

48
Q

The elements of group IIA are the…

A

Alkaline earth metals

49
Q

Alkaine earths have a LARGER/SMALLER atomic radius than alkali metals

A

Smaller.

50
Q

Can the two valence electrons of alkaline earths be removed to form divalent cations?

A

Yes.

51
Q

Alkaline earths have _____ IEs

Alkaline earths have _____ electron affinities

A

Alkaline earths have LOW IEs

Alkaline earths have LOW electron affinities

52
Q

Elements in group VIIA are the…

A

Halogens

53
Q

Halogens have ____ reactivity

Why?

A

Halogens have HIGH reactivity

Seven electrons in the valence shell

54
Q

In terms of physical properties, are the halogens uniform or diverse?

A

Halogens are highly variable.

F2 and CL2 are gaseous, Br2 is liquid, I2 is solid at room temperature

55
Q

Are the chemical properties of halogens uniform or diverse?

What group of elements are halogens most reactive with?

A

Uniform.

High electronegativities, high ionization energies

Alkali Metals and Alkaline Earth metals (group IA and IIA)

56
Q

The group of elements found in group VIIIA are the…

A

Noble Gases

57
Q

The noble gases are REACTIVE/NONREACTIVE
The noble gases have HIGH/LOW IEs
The noble gases have HIGH/LOW electronegativities

Why?

A

NONREACTIVE
HIGH IEs
NO ELECTRONEGATIVITIES

Noble gases have a full valence shull

58
Q

Groups IB to VIIIB are the

A

Transition metals.

59
Q

The transition metals are very SOFT/HARD
The transition metals have HIGH/LOW melting points
Transition elements have HIGH/LOW IEs

A

The transition metals are very HARD
The transition metals have HIGH BPs
The transition metals have LOW IEs

60
Q

Transition metals may exist in a variety of positively charged forms, aka

Why?

A

Oxidation states

Transition metals are capable of losing various numbers of electrons from the s and d orbitals of the valence shell

61
Q

Dissolves ions of transition metals can form ____ with other molecules of water or with nonmetals

Does the formation of complex ions increase or decrease the solubility of a compound?

A

Complex Ions

It enhances the solubility

62
Q

What gives the complex ions their characteristic colors?

A

The d orbitals split into two energy sublevels, enabling complexes to absorb certain frequencies of light. Those not absorbed are observed.