gen Chem pg 5 Flashcards
ideal gas law
PV=nRT
density of a gas
density= PM/RT
another formula with density in it
M= dRT/P
combined gas law
PV/T = PV/T
avogadro principle
n/V= k
or n/V = n/V
boyles law
PV= PV (hyperbolic V P graph)
charles law
V/T=V/T
linear graph
guy lussacs law
P/T= P/T linear graph
daltons law
P total= P of a + P of b etc
daltons law particle pressure from P total
P of gas= X of gas (P total)
X is mole fraction
mole fraction of A
mol A/ total moles
henrys law
[A]= kH (P of A)
or [A]/P= [A]/P
average kinetic energy of gas
KE= 1/2 mv^2 = 3/2 kB T
kB is boltzmann constant
root mean square speed
= square root of (3RT/M)
grahams law
rate= 1/square root M
or rate 1/rate 2 = square root (M2/M1)
smaller moves faster
van der walls equation of state (deviation from ideal gas)
takes into account intermolecular attraction and molecular volume
P= (nRT/V-nb) - (n^2 a /V^2)
P is directly prop to -a
ideal gas is most ideal at
high T and low P
gas deviates from ideal at
low T, high P (small V)
diatomic
Br I N Cl H O F
gases at room temp
N Cl H O F
Blood pressure is
< 120/80
constant R
0.08 L atm/mol K
or 8.3 J/mol K
or 8.3 L kPa/mol K
Pressure =
force/area = N/m^2
= Pascal
STP
273 K