Gen chem 4 Flashcards

1
Q

why dont ionic compounds form true molecules

A

ionic compounds dnt form true molecules because of the way oppositely charged ions arrange themselves in the solid state

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2
Q

what is avogadro number

A

6.022 x 10^23

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3
Q

what is the value for one mole of carbonic acid if its mass is 62 amu?

A

one mole of the compound has a mass of 62 grams

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4
Q

what is the molar mass and what are the units

A

the molar mass is the mass of one mole of a compound; g/mol

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5
Q

how do you find the number of moles of a sample substance

A

mass of sample(g)/molar mass(g/mol) = moles

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6
Q

how do you find the gram equivalent weight and how do you use it to find the number of equivalents?

what is the gram equivalent weight
what is an equivalent(hint: question)

A

gram equivalent weight= molar mass/n(n is the number of particles of interest produced or consumed in the rxn
equivalents= mass of the compound(g)/gram equivalent weight

gram equivalent weight is the amount of a compound in grams that produces one equivalent of the particle of interest
equivalent: how many moles of the thing that we want(particle of interest) will be produced by one mole of a given substance

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7
Q

what is normality, how is it used on the mcat

A

a measure of conc, given in equivalents per liter

it is used for hydrogen ion concentration

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8
Q

what conc of hydrogen ions will a 1 N soln of acid contain?

A

a 1 N soln of acid will contain a conc of hydrogen ions equal to 1 mol/L

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9
Q

in a 1 N soln of HCL, why is the molarity one?

how do normality and molarity relate in an eqn?

A

M is 1 because HCL is a monoprotic acid

Normality/n=Molarity(n is the number of protons, OH ions, electrons or ions produced or consumed by the solute)

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10
Q

how many equivalents of base are needed to neutralize both protons in carbonic acid

A

2 becuz its diprotic

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11
Q

in acid-base chemistry, what two things does the gram equivalent weight represent

A

the gram equivalent weight represents the mass of acid that yields one mole of protons and there mass of base that yields one mole of OH ions

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12
Q

what is percent composition and how is it calc’d?
what other two things can you use to figure it out
what can you also figure out given the perc comp and molar mass of a compound

A

percent composition of an element (by mass) is the percent of a specific compound that is made up of a certain element
perc. comp of a element in a cmpd is
mass of an element in formula/molar mass x 100= percent comp

you can also use the empirical or molecular formula to figure this out

can figure out the molecular formula

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13
Q

what is a: combination reaction, decomposition reaction(and 3 ways it can be caused)
how can you recognize a decomp rxn(what does it have more of?)

A

combination rxn is when 2 or more reactants form one product
decomp rxn is the opposite of a combination rxn; its wen one product becomes 2 or more products(can be caused by heating, radiation, or electrolysis)\
decomp rxns have more products than reactants

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14
Q

what is a combustion rxn

what two products does this rxn make

A

it involves a fuel(usually a hydrocarbon) and an oxidant(normally oxygen)
it makes Co2 and water

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15
Q

what is a single displacement rxn

what is it also called

A

happens when an atom or ion in a cmpd is replaced by an atom or ion of another element
also known as redox rxn

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16
Q

what type of reaction is this?

Cu (s) + AgNO3 (aq) > Ag (s) + CuNO3 (aq)

A

single displacement rxn

17
Q

what is a double displacement rxn, why does this rxn occur

what is it also called

A

elements from two different cmpds swap places with each other to make two new compounds
this reaction occurs when one of the products is removed from the soln as a precipitate or gas or when two of the original species combine to form a weak electrolyte that stays undissociated in soln
-metathesis rxn

18
Q

what is a neutralization rxn, what type of rxn is it

A

an acid reacts with a base to make a salt and usually, water (type of double displacement rxn)

19
Q

how to balance equations (get some steps from youtube

A

look on youtube

20
Q

3 steps to solvgin stoichiometric coefficients

A

convert given units to moles, use the mole ratio, convert from moles to the desired units

21
Q

when one reactant is used up or consumed first, what is it called AND why is it called limiting?

A

the limiting reagent

its called limiting because it limits the amount of product that can be formed in the rxn

22
Q

what are the reactants called that remain after all the limiting reagent is used up

A

excess reagents

23
Q

what are two things to keep in mind about figuring out the limiting reagent?

A
  • all comparisons of reactants must be done in units of moles, not grams!!!!
  • you can just use the absolute mole quantities of the reactants; you need to use the stoichiometric ratios of the reactants combined with the absolute mole quantities to see which reactant is the limiting reagent
24
Q

what is the yield of a reaction(what two yields are there)

A

the yield can be theoretical(predicted) or actual yield

25
Q

what is theoretical yield(what three things do u have to assume when getting the theoretical yield)
how do you find the percent yield

A

its the max amount of product that can be generated as predicted from the balanced equation, assuming all of the limiting reactant is used up, no side reactions have occurred, and the entire product has been collected
actual yield/theoretical yield x 100= percent yield

26
Q

how do you name elements(usually metals) that can form more than one positive ion
how do you name monoatomic ions
when an element forms two oxyanions,how do you name them?

A

you name the metal and put the charge in roman numerals in parentheses

  • monoatomic ions are named by dropping the ending of the name and adding -ide to it(F- is Flouride)
  • the name of the one with less oxygen ends in -ite, and the one with more oxygen ends in -ate(NO2 Nitrite, NO3 Nitrate)
27
Q

how are extended series’ of oxyanions named

A
use the prefixes hypo and hyper(written as per)
ClO hypochlorite
ClO2 chlorite
ClO3 chlorate
ClO4 perchlorate
28
Q

what do transition metals of MnO4 and CrO4 2- have high what and what happens to reduce it and make them good whats?

A

they have high oxidation numbers on the metal AND as such they gain electrons in order to bring the oxidation number down to make them good oxidizing agents!!!!!!

29
Q

what kind of ox state do the oxyanions of halogens have

A

they have a positive ox state

30
Q

why are the solid ionic compounds tend to be poor conductors of electricity

A

becuz the charged particles are rigidly set in place by the lattice arrangement of the crystalline solid

31
Q

what is the meaning of solvate

A

to solvate is the tendency of an ionic solute to dissolve

32
Q

what is a strong electrolyte

A

its strong if it dissociates into its constituent ions

33
Q

three examples the book mention of strong electrolytes

A

NaCl, KI, and molecular compounds with highly polar covalent bonds that dissociate into ions when dissolved

34
Q

4 exampls the book mentions of weak electrolytes

A

acetic acid and other weak acids, and ammonia and together weak bases

35
Q

define a nonelectrolyte and examples(3 specific by name)

A

compounds that dont ionize at all in water, retaining their molecular structure in soon, which may limit their solubility
-ex’s: many nonpolar gases and organic compounds like O2, CO2 and glucose

36
Q

what compounds are the weakest and why

A

nonpolar covalent compounds(becuz they dnt form current-carrying ions