Gen chem 2 Flashcards

1
Q

rows of the periodic table are called?

A

periods

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2
Q

columns of the PT are called ?

A

groups or families

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3
Q

electrons located where have the highest potential energy?

A

they are located in the valence shell

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4
Q

Offhand, what are the electron configurations for chromium and copper`

A

for chromium its 4s^1 3d^5

for copper its 4s^1 3d^10

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5
Q

what element is a metal but not considered lustrous and why?

A

mercury, because its a liquid under standard conditions

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6
Q

name ten qualities of metals, starting with high melting point?
Also what quality about metals do many of these characteristics point to?

A

high melting point, high densities, malleable, ductile,

Low effective nuclear charge, low electronegativity(high electropositivity), large atomic radius, small ionic radius, low ionization energy, low electron affinity(these qualities point to how metals lose electrons easily

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7
Q

what quality about the valence e-‘s of metals makes them good conductors of heat and electricity

A

its because their valence electrons are loosely bound to atoms

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8
Q

where are the valence electrons of active metals, transition metals, actinides and lanthanides

A

s subshell; s and d subshells, s and f subshells

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9
Q

name 9 qualities of nonmetals

A
brittle
high ionization energy
high electron affinity
high electronegativity(low electropositivity)
small atomic radius
large ionic radius
poor conductors of heat
poor conductor of electricity
doesn't give up electrons easily
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10
Q

name the metalloids

A

boron, silicon, germanium, arsenic, antimony, tellurium, polonium, and astatine

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11
Q

how does the positivity of the nucleus increase? and with this what force increases?what charge is known as?

A

it increases from left to right, because protons increase with atomic number!
also, because this positivity is increasing, the electrostatic attraction between the valence electron shell electrons and the nucleus will increase(this is called the effective nuclear charge)

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12
Q

what is the zeff a measure of? how does zeff increase on the PT?

A

the zeff is a measure of the net positive charge experienced by the outermost electrons—this pull is done by the inner electrons
-zeff increases from left to right within a period

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13
Q

why are valence electrons held less tightly as you move down a group

A

this is due to the increased separation between the valence electrons and the nucleus

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14
Q

what is the atomic radius?

how it increase?

A

atomic radius of an element is equal to one-half of the distance btween the centers of the two atoms of an element that are briefly in contact with each other
atomic radius increases from right to left

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15
Q

what does ionic radius depend on?

A

it depends on how the element ionizes based on its element type and group number

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16
Q

what does the group number of nonmetals close to the metalloid line tell us?

A

their group number tells us that they need more electrons than other nonmetals to get to an electronic configuration like the ones the inert gases have

17
Q

how do metals close to the metalloid line achieve an inert gas like electronic configuration

A

they need to lose electrons for this to happen

18
Q

why do metals close to the metalloid line have a greater ionic radius than inert gases?

A

they do because they lose electrons

19
Q

what is ionization energy

A

it is the energy required to remove an electron from a gas species

20
Q

is removing an electron from an atom exo or endothermic

A

endo, it always requires energy

21
Q

what is a reason that valence electrons are tightly bound to an atom
how does this affect the ionization energy

A

atom has a high zeff, which means that the atom’s valence electrons are close to the nucleus
this makes it difficult to remove electrons and increases their ionization energy

22
Q

how does ionization energy increase in a period and a group in the PT

A

goes up from left to right in a period and top to bottom in a group

23
Q

why are elements in groups 1 and 2 called the active metals

A

they are called the active metals because they have lo ionization energies

24
Q

how many electrons in groups 1 and 2 need to lose to get an octet

A

group 1 needs to lose 1; group 2, 2

25
Q

what does the number of electrons that an atom loses tell you about it

A

if it loses electrons and it gets a noble gas like electron configuration, then losing one more electron will cost much more energy

26
Q

what is electron affinity

A

electron affinity is energy disspated by a gas species when it gains an electron and is the opposite of ionization energy

27
Q

what two things determine how big the energy release will be when an atom gets an electron, in regards to electron affinity
how does electron affinity increase in groups and periods

A

the stronger the electrostatic pull or the higher the zeff between the nucleus and the valence electrons, the greater the energy the release will be when an atom gets an electron
electron affinity increases from left to right and goes down from top to bottom

28
Q

describe the trend of electron affinity for elements in groups 1 and 2 and for the halogens

A

its low in the groups 1 and 2 and prefer to give up electrons to get the octet of the noble gas in the previous period
its high in the halogens becuz they only need to get one electron to have an octet like the noble gas in the same period

29
Q

why is the electron affinity of the noble gas on the order of zero

A

becuz they already have an octet and cannot readily accept an electron

30
Q

what is electronegativity

A

its a measure of an attractive force that an atom will have an electron in a chemical bond and the greater it is the more it attracts electrons inside the bond

31
Q

how do ionization energy and electronegativity relate

A

the lower the IE, the lower the elecneg

32
Q

what elements have the least and most electronegativity and what are their values on the pauling scale
how does elec neg increase

A

0.7 for Cs, 4.0 for F

it increases from left to right and bottom to top

33
Q

Describe periodic trends in a shorthand style

A
Left to right:
Atomic radius dec
IE inc
Elec aff inc
elecneg inc
top to bottom
Atomic radius inc
IE dec
Elec aff dec
elecneg dec                 *atomic radius is always opposite the other trends
34
Q

what metals have the lowest densities

what results when group 1 metals react with water

A

alkali metals

forms strong bases

35
Q

compare the atomic radii and effective nuclear charge of group 1 and 2 metals

A

group 2 metals have a higher zeff and a slightly smaller atomic radii

36
Q

what are the elements in group 6a called and how many electrons do they have
what is the size of their atomic and ionic radii

A

they are called chalcogens and they have 6 valence electrons

they are small and large

37
Q

what are the states of matter of the halogens

A

gas f2 CL2
LIQUID BR2
SOLID I2

38
Q

frequencies not absorbed are called

and what we see is absorbed or reflected

A

subtraction frequencies

what we see is reflected