Gen Chem Flashcards

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1
Q

Colligative property

A

depends on number of solute particles in given volume of water

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2
Q

FP depression of an aq solution is a ___ property. What does this mean?

A

colligative;

If there are more solute particles, then the FP is lower

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3
Q

1/2 equivalence point

A

for weak acids
[Ha] = [A-]
[H3O+] = Ka
pH = pKA

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4
Q

Catalysts can increase the rate of reaction without…

A
  • incr number of collisions
  • KE of reactants
  • Keq of rxn
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5
Q

Elemental sulfur

A

S or S8

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6
Q

Combustion always involves which reactant?

A

O2

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7
Q

CH3COO -

A

acetate

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8
Q

NH4+

A

ammonium

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9
Q

NH3

A

ammonia

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10
Q

CO3 2-

A

carbonate

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11
Q

ClO3 -

A

chlorate

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12
Q

ClO2 -

A

chlorite

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13
Q

CrO4 2-

A

Chromate

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14
Q

CN -

A

cyanide

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15
Q

Cr2O7 2-

A

Dichromate

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16
Q

HCO3 -

A

bicarb

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17
Q

HSO4 -

A

Bisulfate

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18
Q

HS -

A

bisulfide

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19
Q

HSO3 -

A

bisulfite

20
Q

ClO -

A

Hypochlorite

21
Q

NO3 -

A

Nitrate

22
Q

NO2 -

A

Nitrite

23
Q

ClO4 -

A

Perchlorate

24
Q

MnO4 -

A

Permanganate

25
Q

PO4 3-

A

Phosphate

26
Q

PO3 3-

A

Phosphite

27
Q

SO4 2-

A

sulfate

28
Q

SO3 2-

A

Sulfite

29
Q

HNO3

A

Nitric acid

30
Q

CH3COOH

A

acetic acid

31
Q

for spontaneous reactions, cell voltage is positive / negative?

A

positive (E_cell > 0 & G < 0)

32
Q

equilibrium & reaction quotient expressions do not include…

A

pure solids & liquids

33
Q

Which compounds when added to a saturated solution of KNO3 would cause crystals to precipitate? Why?

A

Compounds with common ion (K+ or NO3-).

-> common ion effect

34
Q

Avogadro’s number

A

6.02 x 10^23

35
Q

strength of base depends on…

A

Stronger base:

  • less EN
  • higher (-) charge
36
Q

Catalytic amount

A

compound is regenerated in a later reaction and can be reused over and over again

37
Q

Why are pure liquids omitted from Keq calculations?

A

because their concentrations remain essentially constant

38
Q

HH

A

pH = pKa + [conj base] / [weak acid]

39
Q

in electrochemical cells, what becomes a gas?

A

the reduced compound

40
Q

Higher / lower [solute] will have a higher BP?

A

Higher

41
Q

Ag tends to always be reduced / oxidized?

A

reduced

42
Q

Cu tends to always be reduced / oxidized?

A

oxidized

43
Q

Ksp

A

Solubility Product Constant

Pretty much Keq but used for solubility purposes

44
Q

Ksp changes if ___ is changed

A

Temperature, and nothing else.

45
Q

vapour ____ changes depending on the size of the container

A

rate of vaporization