Gasoline & Vehicles, Batteries, & Nuclear Power Flashcards
What are covalent compounds?
Are compounds where two non-metals share electrons to achieve a full octet
How are Hydrocarbons named?
They are named based on the amount of Carbon atoms they have
1 = Methane
2 = Ethane
3 = Propane
4 = Butane
5 = Pentane
6 = Hexane
7 = Heptane
8 = Octane
9 = Nonane
10 = Decane
How are Lewis Structures created?
Only the valence electrons are involved in bonding
How are Octane ratings assigned?
Since Octane doesn’t knock, its Octane rating is 100
Heptane however knocks a lot, its Octane rating is 0
A gasoline sample of 87% octane and 13% heptane would give the gasoline a rating of 87%
How is biodiesel made?
It’s made from vegetable oils and animal fats
How is carbon monoxide caused?
Carbon monoxide is produced from the incomplete combustion of carbon
It’s caused when there is insufficient oxygen, or when the catalytic converter is not working properly
How is hydrocarbon pollution produced?
Hydrocarbon pollution is released from burning gasoline if the combustion is incomplete, and there is poor catalytic conversion
How is Nitrogen Oxide (NOx) produced?
It is produced during the combustion of fossil fuels (like gasoline) because the reaction temperatures are high enough to oxidize the atmospheric Nitrogen
How is petroleum refined? and what is the process?
Petroleum refining is done in a process called fractional distillation
Fractional distillation involves the separation of a liquid mixture into different compounds based on their boiling points/volatility
How to prevent engine knocking?
The air-fuel mixture that enters the piston must be a carefully regulated mixture hydrocarbons to ensure there is no engine knocking
The Branched hydrocarbon “octane” has little tendency to knock
What are Catalytic Converters?
Catalytic converters are devices built into the automobile exhaust system. It uses catalysts to reduce the emissions of hydrocarbons, carbon monoxide, and other pollutants
What are Octane Ratings?
Octane ratings is a measure of how well the the fuel doesn’t knock
For example: Gasoline with higher octane rating (Octane 93) tend to knock less than gasoline with lower octane rating (Octane 89)
What are the three Impacts of Climate Change?
- Increased flooding
- Increased drought
- More frequent and more intense hurricanes
What are the three results if humans are exposed to Nitrogen Oxide (NOx)?
Even at low concentrations, nitrogen oxide can irritate and cause severe respiratory problems by:
- Causing inflammation within the lining of the lungs
- Reduces immunity to lung infections
- Wheezing, coughing, colds, flu and bronchitis can result
What eventually happened to tetraethyllead?
Because of it, leaded gasoline were prohibited in most places which led to tetraethyllead to get replaced by other additives that improved octane rating
One of these additives were methy tert-butyl ether (MTBE) and ethanol
What happens if humans are exposed to carbon monoxide?
It is known to be a tasteless and odourless gas (Otherwise known as “The Silent Killer”)
The carbon monoxide enters the body through inhalation, and binds to the hemoglobin in blood (as it has 200-250x more affinity compared to oxygen) causing a decrease of oxygen delivery to all organs within the body, mainly targeting the brain and heart
What happens if humans are exposed to Hydrocarbon pollution?
Is a respiratory and eye irritant. Can cause lung disease in higher concentrations
What happens if humans are exposed to Particulate Matter Pollution?
Is a respiratory irritant
What happens if the Catalytic Converters don’t work properly
Chemical pollution called carbon monoxide will be emitted into the environment
What is a catalyst? (Used in Catalytic cracking)
Catalysts are substances (often specialized metals) that are used to speed up a chemical process without it being consumed
What is an organic compound and a hydrocarbon
Organic Compounds: A covalent compound that contains carbon
Hydrocarbon: A compound that only consists of hydrogen and carbon
What is biodiesel?
Biodiesel is a form of fuel that is similar to petroleum-derivative diesel fuel
What is Canada’s Petroleum refining capacity?
Canada’s total refining capacity is 295,000 cubic meters per day
What is Catalytic Cracking?
Catalytic cracking is a refining process that uses catalysts to break (cracks) longer hydrocarbon chains into smaller hydrocarbons
What is Catalytic Polymerization
This process involves sticking smaller hydrocarbon chains into larger hydrocarbon chains
This is the opposite of Catalytic cracking
Methane + Ethane = Propane
What is Catalytic Reforming
This is a petroleum process where catalysts convert’s straight-chain hydrocarbons into branched hydrocarbons
What is Diesel?
Diesel is made up of hydrocarbons (like gasoline) but is more closer to C12H24 than octane
What is Engine Knocking?
A metallic pinging sound that can be heard within automobile engines, when the air-fuel mixture combusts erratically in pockets (in other words not smoothly)
This results in a loss of power, and inefficient and uneconomical use of fuel
What is Nitrogen Oxide? (NOx)
NO2 is a highly toxic brown gas which is responsible for the brown colour in Toronto during smog days
What is Particulate Matter Pollution
This pollution are dust particles that appear as smoke during the process of burning gasoline and other fossil fuels
What is Petroleum? How did it get it’s name? What can it be refined into?
Petroleum is an oily, flammable liquid that has a mixture of hundreds of hydrocarbons and other minor components
The name itself is derived from two Latin words:
Petra: meaning rock
Oleum: meaning oil
Petroleum is also known as crude oil, which can be refined into either gasoline, kerosene, diesel, heating oil, and jet fuel
What is tetraethyllead
During the 1920s, an octane rating enhancer called tetraethyllead was added gasoline, which increased the octane rating by 10-15 points
Because of this, it sparked an era of leaded gasoline
What is the 4-Stroke Cycle in a Car Engine?
Intake: The air-fuel mixture enters the cylinder as the piston moves downwards
Compression: The air-fuel mixture becomes compressed as the piston moves upwards
Power: The spark plug fires, which causes an explosion that forces the piston downwards
Exhaust: As the piston moves up, it forces exhaust gasses out of the cylinder
What is the benefit of Diesel?
Diesel vehicles are more fuel efficient in comparison to gasoline vehicles because there is less fuel required per km of travel
What is the Greenhouse Effect?
The Greenhouse Effect is when all gasses within the Earth’s atmosphere traps the sun’s heat, which makes Earth warmer than it would be without the atmosphere
What is the problem of Diesel?
In comparison to gasoline, Diesel produces more CO2 as it produces 2.7 kg of CO2 whereas gasoline only produces 2.3 kg of CO2
In other words, Diesel produces more NOx and particulate matter
What is the problem with fractional distillation? How is this solved?
Distillation is not efficient enough to produce enough gasoline to power all vehicles in the world
And only 20% of any petroleum (crude oil) actually consist of the correct hydrocarbons for it to produce gasoline
This can be solved by using catalysts
What is the problem with Greenhouse gasses?
If more Greenhouse Gasses are released into the atmosphere, it can result in an unnatural increase of amount of energy being absorbed by the atmosphere
This results in a disruption of energy balance and in turn increases temperature
What is the process in a Diesel-powered engine?
A diesel powered engine is similarily designed to a gasoline-powered engine
The 4 steps are:
- Intake: air only
- Compression: air is compressed, causing it to heat up
- Power: Diesel fuel is injected exactly when the air heats up to ignite (No spark plugs used)
- Exhaust: (same as gasoline)
What is volatility?
Volatility is a measure of how well a substance evaporate (turn from liquid to gas)
In other words, substances with low boiling points have high volatility
What was the problem of tetraethyllead and what was the solution to this?
During the 1950s, it was observed that there was an increasing number of vehicles that were emitting noxious exhaust gasses which were unburned hydrocarbons (like carbon monoxide) and gasoline impurities (like suplur and nitrogen)
The solution for this problem was Catalytic Converters
What would happen if there are no Greenhouse gasses?
Because Greenhouse gasses are natural and vital for Earth, if there were no greenhouse gasses, the temperature on Earth would be -18 degrees
What’s the problem with Catalytic Cracking?
Even though we’re able to create more smaller hydrocarbon chains, we waste the larger hydrocarbon chains that could’ve been used for other applications like kerosene for heating
Why can’t unprocessed vegetable oils be used as fuel?
Because engines require significant modifications, which cannot be fulfilled from vegetable oils
Why is it better to have branched hydrocarbons compared to straight hydrocarbons?
Branched hydrocarbons were observed to have a better tendency to burning smoothly, and resisting engine knocking
How is biodiesel used?
Biodiesel can be used by blending it with petroleum diesel
What is B5? What is B100?
B5 stands for 5% biodiesel blend and B100 stands for 100% biodiesel blend
What are the 4 types of biomass energy?
- Wood
- Bioalcohols
- Biodiesel
- Municipal Waste
What is Bioalcohol: Ethanol?
Are light alcohols which are by-products of the distillation of petroleum, or by the fermentation of sugar containing biological materials
What can Bioalcohol: Ethanol be used for?
Can be used as a source of energy, and since they’re liquid, they can be a convenient replacement for petroleum-based transportation fuels like gasoline
How common is Bioethanol?
95% of all ethanol is Bioethanol, while the remaining 5% is produced from petroleum
What is Bioethanol mostly used for
Mostly used for the production of energy
Three step process of Bioethanol
- Sunlight first produces glucose by photosynthesis
6CO + 6H2O + light -> C6H12O6 + 6O2 - Fermentation of glucose produces ethanol:
C6H12O6 -> 2C2H5OH + 2CO2 + heat - Combustion of ethanol produces heat
C2H5OH + 3O2 -> 2CO2 +3H2O + heat
What’s the problem with using Bioethanol as power?
Because photosynthesis is inefficient, the electricity from burning ethanol in a heat engine has an overall efficiency that is considerably lower than what can be achieved using photovoltaics (EVs)
What is 2 ways Ethanol is used in fuel?
It’s pure form can either be in a combustion engine, or be blended with gasoline
How much Ethanol can you use in a gasoline mixture?
Only 10% before the engines begins to requiring modifications