gas laws Flashcards
0
Q
- what is CHARLE’S law of gasses?
- how is it stated mathematically?
- what temp constant must be used?
A
- CHARLE’S LAW: think “CP” pressure is the constant with charles law.
- -at a constant pressure, the volume of a gas is directly proportional to the temp (temp=k).
- -gasses expand when warmed and shrink when cooled - V1/T2=V2/T2; V=kT; V/T=k
- must first convert temps to kelvin (k=kelvin temp)
1
Q
- what is BOYLE’S law?
2. how do you calculate it?
A
- BOYLE’S LAW: think “TB” temp constant with boyle’s
at a constant temperature, volume is inverse to pressure:
– as the pressure goes up, the volume goes down;
–as the pressure goes down, the volume goes up. - P1V1=P2V2; V is proportional to 1/P; PV=k
2
Q
- IDEAL GAS law aka?
- what is the formula?
- how do you interpret it?
A
- combined gas law (combination of charle’s and boyle’s) ideal=combined.
- PV=nRT (R is the constant or IDEAL gas; n= number of moles)
- when n (number of moles) changes, the pressure or volume will change.
3
Q
DALTON’S law of partial pressures:
- what is the formula?
- how does it work?
A
- P Total=P(A) + P(B) + P(C) etc.
- in a gas mixture, each gas exerts its own partial pressure (oxygen=21% of 760 mmHg; nitrogen=78% of 760mmHg)
.21 x 760=159 for O2; .78 x 760=592 for N2
4
Q
- what is the standard for temperature for gas laws?
2. how do you convert to it?
A
- kelvins
- kelvin=celcius + 273
- farenheit to celcius (9 degrees C= 5 degrees F-160), convert farenheit to celcius, then celcius to kelvin.
5
Q
- what is GUY-LUSSAC’S law?
- what is the equation?
- what does it mean?
A
- “vitamin G” volume is the constant in guy lussac’s (it is a modification of charle’s law).
- P1/T1=P2/T2 (or P=kT or P/T=k)
- at a constant volume, pressure of gas increases with temp (if you heat up a tank of gas, it could explode)
6
Q
example of Guy-Tussac’s law:
E cylinder with 1500 psi at room temp (70F) is heated to 350 degrees F by a fire. What is the new pressure?
A
1500 psi at room temp to 350 degrees F
1. 9(C)= 5(70) -160= ; 9(C)= 350-160=; 9(C)=190
9/9(C)=190/9=; C=21 (Kelvin=C+273);
21+273=294 degrees Kelvin; room temp=294 kelvin……NOW…
- 9(C)=5(350)F-160; =9(C)=1750 -160= ; 9(C)=1590
9/9 C= 1590/9=176 degrees celcius
(kelvin=C + 273) 176 Celcius+273=449 degrees kelvin
p1/t1=p2/t2»> 1500/294=x psi/449»>294x psi=673,500»
673,500/294= 2,291 psi
7
Q
what does STP mean?
A
standard temperature and pressure (0 degrees celcius and 1 atm (or 273 degrees K and 760 mmhg))
8
Q
- according to avagadro’s hypothesis, one mole of gas at STP occupies how many liters?
- what does avagadro’s number state?
A
- 22.4 L
- one mole is the quantity of any substance containing the same number of particles as 12 grams. the number of particles is 6.02 x 10 to the 23rd power
9
Q
according to avagadro’s hypothesis; how many grams per 1 mole of each?
- oxygen:
- nitrous oxide:
- how many liters of space does each one occupy?
A
- 1 mole of oxygen=32 grams
- 1 mole of nitrogen=44 grams
- 22.4 L at STP (according to Avagadro’s law)