Forces between Molecules Flashcards

1
Q

What are intermolecular forces?

A

weak forces of attraction between molecules

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2
Q

What are the three types of intermolecular forces?

A

-van der Waals forces
-dipole-dipole forces
-hydrogen bonding

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3
Q

Put each intermolecular force in order of strongest to weakest

A

hydrogen > dipole-dipole > van der Waals

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4
Q

What are van der Waals forces?

A

weak electrostatic attraction produced by positive and negative charges

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5
Q

Where do van der Waals forces occur?

A

between all atoms and molecules

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6
Q

What affects the strength of van der Waals forces?

A

increase with number of electrons

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7
Q

What atoms produce strong van der Waals forces?

A

those with large atomic masses

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8
Q

What molecules may have a dipole moment?

A

those with polar bonds

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9
Q

In which molecules do dipoles cancel?

A

linear and tetrahedral molecules

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10
Q

What is a dipole caused by?

A

changing position of electron cloud

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11
Q

What do dipoles affect?

A

electron distribution in nearby molecules, can induce temporary dipoles

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12
Q

Where do dipole forces act?

A

between molecules with permanent dipoles

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13
Q

What will dipoles do so that two molecules attract?

A

flip their arrangement

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14
Q

What does a hydrogen bond consist of?

A

hydrogen atom between two very electronegative atoms

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15
Q

What conditions are required for hydrogen bonding to occur?

A
  1. very electronegative atom with lone pair
  2. connected covalently to hydrogen atom
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16
Q

How can hydrogen bonding occur in water?

A

-oxygen atom is highly electronegative
-oxygen has a lone pair
-hydrogen atoms electron deficient due to oxygen high electronegativity

17
Q

How is a hydrogen bond shown?

A

a dashed line - - -

18
Q

How is hydrogen charged in a water molecule?

A

delta plus / partially positive

19
Q

How is oxygen charged in a water molecule?

A

delta minus / partially negative

20
Q

How does hydrogen bonding affect the boiling points of the hydrides?

A

generally noble gases shown increase in boiling point as van der Waals forces increase with number of electrons
HOWEVER…
boiling points of H2O, HF and NH3 are higher due to strength of hydrogen bonds