Flotation Flashcards
a method of wet concentration in which separation is effected by
utilizing the difference in Physico-chemical properties of particles of
various minerals
Flotation
separation is made possible by attaching a mineral to a
bubble and letting it float above the bulk phase, leaving the other
“unwanted” mineral submerged
Flotation
froth product is the concentrate
direct flotation
froth product is the tailings
reverse flotation
What are the 2 types of flotation?
direct flotation and reverse flotation
Flotation is UNIQUE among applications in metallurgy, as it
involves all possible interfaces:
– Air-Water (Gas-Liquid)
– Mineral-Water (Solid-Liquid)
– Air-Mineral (Gas-Solid)
Flotation relies on differences in ______________ among minerals to achieve separation.
surface properties
the time it takes a particle to slide around a bubble
contact time
the time required for the particle to penetrate the film and reach
the air in the bubbles
induction time
What are the three main parts of a mechanical cell?
froth zone, quiescent zone, mixing zone
What are the two main arts of the column cell?
Froth zone and collection zone
What are the two main types of cells?
mechanical cell and column cell
used to provide a water-repellant surface on the mineral to be floated
Collector
The collector is composed of two parts with very distinct properties. What are these?
Non-polar end; Polar end
The collector is composed of two parts with very distinct properties. Which one is a hydrocarbon radical or hydrophobic?
Non- polar end
The collector is composed of two parts with very distinct properties. Which one has compounds that have sufficient activity in water or hydrophilic?
Polar end
The collector is composed of two parts with very distinct properties. These are oriented outward forming a hydrophobic pseudo surface while the polar ion or the solidophil group are attached with the mineral surface via chemisorption or ionic bonding
non-polar hydrocarbon group
What are the two mechanisms of adsorption?
Ion exchange and electrochemical reaction
Mechanisms of Adsorption:
ex: Xanthate ions may adsorb onto a particle by replacing sulphate ions on the surface
Ion exchange
Mechanisms of Adsorption:
transfer of electrons from one substance to
another
electrochemical reaction
used to control alkalinity
pH modifiers
modify the mineral surface which cause a particular mineral to float with a collector when it would otherwise not float
activators
– used to lower the floatability of specific minerals
– makes a naturally hydrophobic mineral hydrophilic
Depressants
- these reagents disperse slimes which often agglomerate and cover
the surfaces of larger particles, preventing them from being
recovered
Dispersants