Flavounoids Flashcards

1
Q

Who isolated “Vitamin P” from oranges

A

Albert Szent-Györgyi credited with this isolation.

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2
Q

What is the basic structure of flavonoids

A

γ-benzopyrone

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3
Q

Flavonoids are more common in____ plants

A

Higher

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4
Q

Largest naturally occurring phenols

A

Flavonoids

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5
Q

What is responsible for colors of flowers fruits and occasionally leaves?

A

Flavonoids

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6
Q

What gives petals their color

A

Anthocyanidins

Cyanidine- Red Delphinidine-Blue

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7
Q

Flavonoids can occur as free state and as glycosides

T or F

A

True

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8
Q
• The
yellow
anthochlor pigments of anthocyanadines
are
produced
from?
A

chalcones and aurones.

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9
Q

Glycosidic flavonoids are soluble in?

Genins are soluble in??

A

Polar solvents

Aglycone - non polar organic

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10
Q

What makesflavonoids good antioxidants and what increases its antioxidant capacity

A

ability to chelate Fe2+ and Cu2+ and scavenge free radicals renders them very good antioxidants.
• The greater the number of hydroxyl groups the greater the antioxidant capacity of the flavonoid.

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11
Q

What are the types of flavonoids based on

A

Degree of oxidation of C ring and hydroxylation of C-3

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12
Q

What are the four o glycosides if flavonoids

A

Quercetin, Kaempferol, Myricetin, Rutin.

KuMyRuQuer
Kumerica

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13
Q

colourless pigments in the leaves of plants
They are building blocks of anthocyanins
• Beverages such as tea and red wine are also important sources

A

Flavanols

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14
Q

What polymethoxylated flavones are the peels of citrus fruits rich in

A

Tagretin Nobiletin sinensetin

TNOS
The nose

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15
Q

What are the three examples of flavones

A

Luteolin Apigenin Chrysin

LAC

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16
Q

Present in all the citrus fruits and responsible for bitter taste of citrus fruit peels

A

Flavanones

17
Q

What are the three flavanones

HEN

A

Hesperitin
Naringenin
Eriodictyol

HEN

18
Q

Predominantly found in legumes and soyabeans

Occur in mycobacterium phlei

A

ISO-flavonoids

19
Q

What are the three iso-flavonoids

A

GDP

Genistein
Daidzen(phytoestrogens)
Prunetin

20
Q

The 5 anthocynanides

A
Cyanidin
Delphinidin
Malvidin
Pelargonidin
Peonidin
21
Q

Characterized by the absence of the 2nd ring of the basic structure and referred to as open chain flavonoids.

A

Chalkones

Eg include Phloridzin, Arbutin, Phloretin, Chalconaringenin

22
Q

Also referred to as “condensed tannins”

Responsible for astringency in many foods and medicinal herbs

A

Proanthocynanide

23
Q

are basically flavanols.
There are two chiral centers on the molecule; Carbons 2
and 3. Therefore, it has four diastereoisomers.

A

Flavan-3-ol

24
Q

What color do flavonoids give for FeCl3 Alkalis and AlCl3 and what makes them give those colors

A

Blue colour with FeCl3
Yellow colour with Alkalis
Yellow colour with AlCl3

Flavonoids contain the benzopyran nucleus, and occur either as aglycones or as
glycosides.
• The aglycones are pale yellow and their glycosides are colourless.