First Law of Thermodynamics (Closed System) Flashcards

1
Q

form of energy that is transferred between two systems (or a system and its surroundings) by virtue of a temperature difference

A

heat

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2
Q

state functions

A

Pressure, Temperature, Volume, Mass, Internal Energy

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3
Q

Conditions for reversibility

A

Absence of friction
Quasi-static process
No heat loss
Ideal fluid

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4
Q

based on the law of conservation of energy

A

first law of thermodynamics

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5
Q

path functions

A

heat and work

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6
Q

performed whenever a force acts through a distance

A

work

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7
Q

energy that a system possesses as a result of its elevation in a gravitational field

A

potential energy

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8
Q

Real world thermodynamic processes are?

A

irreversible

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9
Q

thermal energy transferred to or from the system to overcome the intermolecular forces between the molecules resulting to a phase change

A

Latent energy or Latent heat

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10
Q

energy that a system possesses as a result of its motion relative to some reference frame

A

kinetic energy

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11
Q

represents the heat storage capability of a material

A

specific heat

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12
Q

defined as the energy required to raise the temperature of a unit mass of a substance by one degree

A

specific heat

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13
Q

sum of the internal energy and flow work

A

enthalpy

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14
Q

the internal energy of a system associated with the kinetic energies of the molecules

A

sensible energy

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15
Q

a process whose direction can be reversed by infinitesimal changes in some properties of the surroundings, such as pressure

A

reversible process

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16
Q

four components of internal energy

A

sensible, latent, chemical, and nuclear

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17
Q

sum of all the microscopic forms of energy

A

internal energy

18
Q

the energy required to raise the temperature of a unit mass of a substance by one degree as the volume is held constant

A

Specific heat at constant volume

19
Q

Constant Temperature

A

ISOTHERMAL PROCESS

20
Q

a process in which the system and the surroundings do not return to their original condition once the process is initiated

A

irreversible process

21
Q

thermal energy transferred to or from the system to overcome the intermolecular forces between the molecules resulting to a phase change

A

Latent Heat

22
Q

refers to the process where an ideal gas expands into a vacuum without any resistance, work being done, or heat transfer

A

free expansion of an ideal gas

23
Q

consigned the caloric theory of heat to a footnote in history

A

Joule’s experiment

24
Q

“The energy of a thermodynamic system in equilibrium is partitioned equally among its degrees of freedom.”

A

equipartition theorem

25
Q

Constant Volume

A

ISOCHORIC PROCESS

26
Q

It is recognized only as it crosses the boundary of a system

A

heat

27
Q

An idealized concept that serves as a theoretical benchmark for understanding real processes.

A

reversible process

28
Q

the energy required to raise the temperature of a unit mass of a substance by one degree as the pressure is held constant

A

Specific heat at constant pressure

29
Q

refer to the sensible and latent forms of internal energy

A

thermal energy

30
Q

the internal energy associated with the atomic bonds in a molecule

A

chemical energy

31
Q

Lavoisier called heat as?

A

calorific fluid

32
Q

what type of function is enthalpy

A

state function

33
Q

𝐶𝑣 and 𝐶𝑝 are dependent of?

A

temperature

34
Q

the internal energy associated with the atomic bonds in a molecule

A

nuclear energy

35
Q

is energy in transition

A

heat

36
Q

the system can be returned to its initial state without any net change in the surroundings

A

reversible process

37
Q

Constant Pressure

A

ISOBARIC PROCESS

38
Q

property whose value doesn’t depend on the path taken to reach that specific value is known as

A

state function or point function

39
Q

thermal energy transferred to or from the system which changes the kinetic energy of molecules resulting to a temperature change

A

Sensible energy or Sensible heat

40
Q

are the mechanisms of energy transfer

A

heat and work

41
Q

Internal energy is related to the?

A

molecular structure and degree of molecular activity

42
Q

the internal energy associated with the intermolecular force of attraction between molecules

A

latent energy