FINAL YO Flashcards
Simplest forms of Carbohydrates are?
Dihydroxyacetone & d- and 1- glyceraldehyde
Carbs are…
polyhydroxy aldehydes and ketones
Fructose can cyclolize into…
pyranose
furanose
Citric Acid Cycle Net Equation
AcetylCoA + Pi + ADP + 3NAD+ + FAD+ = 2CO2 + 3NADH + FADH2 + CoA + ATP + 8e-
Path of E- down ETC
NADH - Complex 1 - CoQ - Complex 3 - Cyt C - complex 4 -O2
FADH2 - complex 2 - CoQ - complex 3 - cyt c - complex 4 - O2
Type of bond between AA and tRNA
Anhydride bond that uses Pi from ATP
Wobble Hypothesis
tRNA molecules bind to more than 1 codon, especially at posistion 3
AA attached to tRNA where?
At 3’ end (CCA)
Peptide bonds are planar due to?
Partial double bond character and are normally trans
Ramachandran Plot
- Shows known config
- Shows rotations of phi and psi angles
Relationship of delta G & delta G knot
Difference from standard state to physiological/actual state depending on concen. of reactants and products
Gibbs free energy of activation is?
Difference in energy from reactants to transition state
Michaelis Menton Equations
Describes variation of enzyme activity as a function of substrate concen.
Km =
substrate @ 1/2 vmax
k-1+k2/k1
Shine delgarno Sequence
Ribosomal binding site upstream of Start sequence in PRO
Cellulose is….
B 1-4 linked
Intermediate molecule formed during EtOH ferm
Acetaldydye
Intermediate molecule of GnG
Glycerol phosphate
Pyruvate Carboxylase (GNG) does what?
converts pyruvate to oxaloacetate
molecules required for GnG
CO2 ATP H2O
Steps of Conversion of Pyruvate to Acetyl CoA
Decarboxylation, oxidation, transfer CoA
Competitive Inhibition
Molecule binds in active site, prevents substrate from binding
- Km = increases
- Vmax = uncahnged
Non-competitive inhibition
Molecule binds OUTSIDE enzyme substrate complex and inhibits
- Km = no change
- Vmax = increases
Uncompetitive Inhibition
Molecule binds to enzyme substrate complex and prevents from moving forward.
- Km = decreases
- Vmax = decreases
Oxidoreductases
Oxidation/reduction RXNS
Transferase
transfer functional groups between molecules
hydrolases
cleaves molecules adding H20
Lyases
adds functional groups to double bonds or removes them to form double bonds
isomerases
moves functional group within molecule
Ligases
join 2 molecules via ATP hydrolysis