FINAL YO Flashcards

1
Q

Simplest forms of Carbohydrates are?

A

Dihydroxyacetone & d- and 1- glyceraldehyde

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2
Q

Carbs are…

A

polyhydroxy aldehydes and ketones

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3
Q

Fructose can cyclolize into…

A

pyranose

furanose

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4
Q

Citric Acid Cycle Net Equation

A

AcetylCoA + Pi + ADP + 3NAD+ + FAD+ = 2CO2 + 3NADH + FADH2 + CoA + ATP + 8e-

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5
Q

Path of E- down ETC

A

NADH - Complex 1 - CoQ - Complex 3 - Cyt C - complex 4 -O2

FADH2 - complex 2 - CoQ - complex 3 - cyt c - complex 4 - O2

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6
Q

Type of bond between AA and tRNA

A

Anhydride bond that uses Pi from ATP

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7
Q

Wobble Hypothesis

A

tRNA molecules bind to more than 1 codon, especially at posistion 3

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8
Q

AA attached to tRNA where?

A

At 3’ end (CCA)

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9
Q

Peptide bonds are planar due to?

A

Partial double bond character and are normally trans

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10
Q

Ramachandran Plot

A
  • Shows known config

- Shows rotations of phi and psi angles

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11
Q

Relationship of delta G & delta G knot

A

Difference from standard state to physiological/actual state depending on concen. of reactants and products

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12
Q

Gibbs free energy of activation is?

A

Difference in energy from reactants to transition state

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13
Q

Michaelis Menton Equations

A

Describes variation of enzyme activity as a function of substrate concen.

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14
Q

Km =

A

substrate @ 1/2 vmax

k-1+k2/k1

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15
Q

Shine delgarno Sequence

A

Ribosomal binding site upstream of Start sequence in PRO

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16
Q

Cellulose is….

A

B 1-4 linked

17
Q

Intermediate molecule formed during EtOH ferm

A

Acetaldydye

18
Q

Intermediate molecule of GnG

A

Glycerol phosphate

19
Q

Pyruvate Carboxylase (GNG) does what?

A

converts pyruvate to oxaloacetate

20
Q

molecules required for GnG

A

CO2 ATP H2O

21
Q

Steps of Conversion of Pyruvate to Acetyl CoA

A

Decarboxylation, oxidation, transfer CoA

22
Q

Competitive Inhibition

A

Molecule binds in active site, prevents substrate from binding

  • Km = increases
  • Vmax = uncahnged
23
Q

Non-competitive inhibition

A

Molecule binds OUTSIDE enzyme substrate complex and inhibits

  • Km = no change
  • Vmax = increases
24
Q

Uncompetitive Inhibition

A

Molecule binds to enzyme substrate complex and prevents from moving forward.

  • Km = decreases
  • Vmax = decreases
25
Q

Oxidoreductases

A

Oxidation/reduction RXNS

26
Q

Transferase

A

transfer functional groups between molecules

27
Q

hydrolases

A

cleaves molecules adding H20

28
Q

Lyases

A

adds functional groups to double bonds or removes them to form double bonds

29
Q

isomerases

A

moves functional group within molecule

30
Q

Ligases

A

join 2 molecules via ATP hydrolysis