FINAL YO Flashcards

1
Q

Simplest forms of Carbohydrates are?

A

Dihydroxyacetone & d- and 1- glyceraldehyde

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2
Q

Carbs are…

A

polyhydroxy aldehydes and ketones

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3
Q

Fructose can cyclolize into…

A

pyranose

furanose

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4
Q

Citric Acid Cycle Net Equation

A

AcetylCoA + Pi + ADP + 3NAD+ + FAD+ = 2CO2 + 3NADH + FADH2 + CoA + ATP + 8e-

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5
Q

Path of E- down ETC

A

NADH - Complex 1 - CoQ - Complex 3 - Cyt C - complex 4 -O2

FADH2 - complex 2 - CoQ - complex 3 - cyt c - complex 4 - O2

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6
Q

Type of bond between AA and tRNA

A

Anhydride bond that uses Pi from ATP

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7
Q

Wobble Hypothesis

A

tRNA molecules bind to more than 1 codon, especially at posistion 3

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8
Q

AA attached to tRNA where?

A

At 3’ end (CCA)

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9
Q

Peptide bonds are planar due to?

A

Partial double bond character and are normally trans

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10
Q

Ramachandran Plot

A
  • Shows known config

- Shows rotations of phi and psi angles

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11
Q

Relationship of delta G & delta G knot

A

Difference from standard state to physiological/actual state depending on concen. of reactants and products

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12
Q

Gibbs free energy of activation is?

A

Difference in energy from reactants to transition state

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13
Q

Michaelis Menton Equations

A

Describes variation of enzyme activity as a function of substrate concen.

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14
Q

Km =

A

substrate @ 1/2 vmax

k-1+k2/k1

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15
Q

Shine delgarno Sequence

A

Ribosomal binding site upstream of Start sequence in PRO

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16
Q

Cellulose is….

A

B 1-4 linked

17
Q

Intermediate molecule formed during EtOH ferm

A

Acetaldydye

18
Q

Intermediate molecule of GnG

A

Glycerol phosphate

19
Q

Pyruvate Carboxylase (GNG) does what?

A

converts pyruvate to oxaloacetate

20
Q

molecules required for GnG

A

CO2 ATP H2O

21
Q

Steps of Conversion of Pyruvate to Acetyl CoA

A

Decarboxylation, oxidation, transfer CoA

22
Q

Competitive Inhibition

A

Molecule binds in active site, prevents substrate from binding

  • Km = increases
  • Vmax = uncahnged
23
Q

Non-competitive inhibition

A

Molecule binds OUTSIDE enzyme substrate complex and inhibits

  • Km = no change
  • Vmax = increases
24
Q

Uncompetitive Inhibition

A

Molecule binds to enzyme substrate complex and prevents from moving forward.

  • Km = decreases
  • Vmax = decreases
25
Oxidoreductases
Oxidation/reduction RXNS
26
Transferase
transfer functional groups between molecules
27
hydrolases
cleaves molecules adding H20
28
Lyases
adds functional groups to double bonds or removes them to form double bonds
29
isomerases
moves functional group within molecule
30
Ligases
join 2 molecules via ATP hydrolysis