Final Review Flashcards
Formal charge
FC = V - N - (B/2)
Where V is the number of valence electrons of the atom in isolation (atom in ground state)
N is the number of non-bonding electrons on this atom in the molecule
B is the total number of electrons shared in bonds with other atoms in the molecule
Example:
London Dispersion forces
temporary dipoles - very weak forces (also called van der waals)
Dipole-Dipole force
between the positive end of a polar molecule and the negative end of another polar molecule
hydrogen bond
between the hydrogen attached to an electronegative atom and an electronegative atom of a different molecule
ion-dipole forces
between the partial charge of a polar molecule and an atom that carries a charge
ionic bond
between a positively charged atom and a negatively charged atom
Hydrophobic effect
The observed tendency of nonpolar substances to aggregate in aqueous solution and exclude water molecules. This occurs because interactions between hydrophobic molecules allow the water molecules to bond more freely, increasing the entropy of the system
Why is water a universal solvent
Water is polar.
It dissociates salts by separating cations and anions and forms new interactions between the water and ions