Final Exam Guide #2 Flashcards
What are the two natural tendencies that govern all thermodynamically favorable processes?
Entropy and Enthalpy
Know reaction rate and factors that affect it
Reaction Rate-Tells how fast reactants change into products.
Factors: Concentration, Temperature, Surface Area, and
Catalysts
Gasses-
A large number of submicroscopic particles (atoms or molecules), all of which are in a constant, random motion.
Liquids-
Particles in liquids are held together by intermolecular forces that balance out their kinetic energy.
Solids-
Particles are always moving or vibrating Have low rates of diffusion Not permeable High Densities Fixed Shapes Definite Volumes Resist Compression
Arrhenius-
Release hydrogen ions (H=) into aqueous solutions
Bronsted-Lowry Acid-
A substance that donates protons
Bronsted-Lowry Base-
A substance that accepts protons
Lewis Acid-
Any substance that can accept a pair of electrons
Lewis Base-
A substance that can donate a pair of electrons
The effect a solute has on a solvent (colligate properties)
New properties of a solution that are different from the solvent. Depends on the number (not type) of particles of solute in the solution.
The effect creates a solution
Molarity =
Moles of solute/liters of solution
Molality=
Moles of solute/Kg of solvent
% by mass=
mass of solute/mass of solution x 100
% by volume=
volume of solute/volume of solution x 100
Reducing Agent:
is a substance that reduces
another substance. Reducing agents are
always oxidized.
Oxidizing Agent:
is a substance that oxidizes
other substances. Oxidizing agents are
always reduced.
Oxidation is the ___ of an electron
loss
Reduction is the __ of an electron
Gain
Reduction makes oxidation numbers
___because there is a gain of electrons
and electrons are negatively charged.
smaller
Oxidation makes oxidation numbers ____
because there is a transfer of electrons.
bigger
Acids:
tart, sour taste, they neutralize
bases, ionize (form ions)
Bases:
taste soapy, bitter, slippery
sensation, ionize
G= ∆H - T∆S
Free Energy Change Equation G= Gibbs free energy H=Enthalpy T=Temperature S=Entropy
-∆G indicates a net ___ in free energy and signifies that a reaction may occur naturally and spontaneously.
Decline
Exergonic reaction
Stronger bonds 🡪 weaker bonds; ∆H > 0
(endothermic)
Weaker bonds 🡪 stronger bonds; ∆H < 0
(exothermic)