Final Exam Flashcards

1
Q

contains a H-bond donor

A

Protic Solvent

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2
Q

does not contain a H-bond donor

A

Aprotic Solvent

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3
Q

two groups are on the same side of a double bond

A

Cis

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4
Q

two groups are on opposite sides of a double bond

A

Trans

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5
Q

molecules that have the same molecular formula but are different in some way

A

Isomers

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6
Q

isomers that differ by rotations about single bonds

A

Conformers

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7
Q

isomers that have different connectivites

A

Constitutional Isomers

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8
Q

the energy increase that appears in an eclipsed conformation

A

Torsional Strain

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9
Q

a molecule that has an IHD of 0 and therefore has the most possible hydrogen atoms given the non-hydrogen atoms it contains

A

Saturated Molecule

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10
Q

a molecule with pi bonds or rings

A

Unsaturated Molecule

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11
Q

isomers that have the same connectivity but are not superimposable

A

Configurational Isomers

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12
Q

isomers that have the same connectivity but are not superimposable

A

Configurational Isomers

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13
Q

configurational isomers that are mirror images of each other

A

Enantiomers

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14
Q

configurational isomers that are not mirror images of each other

A

Diastereomers

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15
Q

has an enantiomer

A

Chiral

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16
Q

does not have an enantiomer

A

Achiral

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17
Q

has 1 stereocenter

A

Chiral

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18
Q

has 2+ stereocenters

A

(could be) Chiral

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19
Q

has no stereocenters

A

(usually) Achiral

20
Q

has no planes of symmetry

A

Chiral

21
Q

has at least one plane of symmetry

A

Achiral

22
Q

molecule that has at least two chiral centers and contains a plane of symmetry

A

Meso

23
Q

clockwise

A

R

24
Q

counterclockwise

A

S

25
Q

higher priority substituents attached to each end of the double bond appear on the same side of the double bond

A

Z

26
Q

higher priority substituents attached to each end of the double bond appear on the opposite side of the double bond

A

E

27
Q

a reaction at equilibrium shifts toward products when the concentration of a reactant is increased or the concentration of a product is decreased; a reaction at equilibrium shifts towards reactants when the concentration of a reactant is decreased or the concentration of a product is increased

A

Le Chatelier’s principle

28
Q

Henderson-Hasselbalch Equation

A

pH = pKa + log ([A-]/[HA])

29
Q

Spectator Ions

A

K+, Na+, Li+

30
Q

electron-rich

A

Nucleophile

31
Q

electron-poor

A

Electrophile

32
Q

when the H atom and the leaving group that are eliminated are anti to each other about the C-C bond involved in the reaction; makes E2 reaction stereospecific

A

Anticoplanar

33
Q

the transition state for a reaction resembles reactants more than products if Gibbs free energy is negative, and it resembles products more than reactants if Gibbs free energy is positive

A

Hammond postulate

34
Q

HCl

A

strong acid

35
Q

HNO3

A

strong acid

36
Q

HBr

A

strong acid

37
Q

H2SO4

A

strong acid

38
Q

HI

A

strong acid

39
Q

HClO4

A

strong acid

40
Q

HClO3

A

strong acid

41
Q

LiOH

A

strong base

42
Q

NaOH

A

strong base

43
Q

KOH

A

strong base

44
Q

Ca(OH)2

A

strong base

45
Q

Ba(OH)2

A

strong base

46
Q

Sr(OH)2

A

strong base