final Flashcards

1
Q

electronegativity trend

A

increases to the right, decreases going down

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2
Q

atomic radius trend

A

decreases from right to left, increases down

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3
Q

sigma bond

A

e- sit between 2 bonded atom, single bonds

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4
Q

pi bond

A

out of plane of molecules, every triple bond, 2 are pi, one is sigma, double bond, one is pi and one is sig

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5
Q

longer the bond

A

lower the energy

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6
Q

photon energy and wavelength equations

A

epho: (planck constant)(frequency)

speed of light = wavelength (frequency)

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7
Q

amorphus solid

A

without structure, no long-range structure, no sharp mp

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8
Q

crystalline solids

A

well-ordered array of atoms or molecules and have wlell defined mp

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9
Q

molecular solid

A

have moderate BP, split apart with IMF’s, formed by molecular compounds, particle type: molecule

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10
Q

network covalent solid

A
  1. have high MP

2. particles are held by VERY strong covalent bonds

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11
Q

ionic solids

A
  1. ionic compounds
  2. lattice pts: cations and anions
  3. breaking ionic bonds (stronger than IMF’s), high MP
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12
Q

metallic solids

A
  1. sea of highly mobile e- and nucleus of particular metal and the core electrons
  2. no generalization of if they all melt high or low
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13
Q

atomic bonds

A
  1. noble gases
    2, lattice pts: atoms
  2. to break, must disrupt dispersion forces
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14
Q

vaporization

A

liquid -> gas, ΔH gas - ΔH liq

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15
Q

condensation

A

gas -> liq, -ΔH vap

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16
Q

fusion

A

solid -> liq, ΔHf liq - ΔH f solid

17
Q

freezing

A

-ΔH fusion

18
Q

sublimation

A

solid - > gas, ΔH f gas - ΔH f solid

19
Q

deposition

A

gas - > solid, -ΔH sublimation

20
Q

high vapor pressure

A

low IMF

21
Q

low vapor pressure

A

high IMF

22
Q

dipole forces

A

only in polar substances

23
Q

hydrogen bonds

A

hydrogen atom is covalently-bonded to a small, highly electronegative atom with the lone electron pairs (N, O, or F)

24
Q

hydrocarbons are always

A

nonpolar

25
Q

dispersion forces

A

universal force in all substances

26
Q

polarizability

A

refers to the shiftability of electrons, generally increases as MM increases

27
Q

substances with the same molar mass…

A

shape differences will determine which has the higher dispersion forces. the stronger dispersion forces will be applied when there can be more points of contact

28
Q

formal charge equation

A

V.E - (lone pairs + 1/2 bonds)