fertilisers Flashcards

1
Q

what does NPK stand for?

A

nitrogen, phosphorous, potassium

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2
Q

why are fertilisers used?

A

to improve agricultural productivity

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3
Q

why is nitrogen important?

A

for cell growth and protein synthesis

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4
Q

why is phosphorous important?

A

DNA synthesis

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5
Q

why is potassium important?

A

to make enzymes involved in respiration and photosynthesis

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6
Q

what are NPK fertilisers?

A

formulations of various salts containing appropriate percentages of the elements

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7
Q

ammonium nitrate equation

A

ammonia + nitric acid —–> ammonium nitrate
NH3 + HNO₃ —-> NH₄NO₃

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8
Q

why is ammonium nitrate a good compound?

A

it has nitrogen from two sources

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9
Q

how are fertilisers made in industry?

A

-reaction is carried out in giant vats, at high concentrations resulting in a very exothermic reaction
-heat released is used to evaporate water from the mixture to make a very concentrated ammonium nitrate product

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10
Q

how are fertilisers made in labs?

A

-reaction is carried out by titration and crystallisation
-reactants are at a much lower concentration than in industry so less heat produced by the reaction so safer
-after titration, mixture is crystallised to give pure ammonium nitrate crystals
-crystallisation isn’t used in industry as it is very slow

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11
Q

what can be used as a source of potassium?

A

potassium chloride and potassium sulphate

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12
Q

what is obtained by mining?

A

-potassium chloride (soluble)
-potassium sulfate (soluble)
-phosphate rock (insoluble)

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13
Q

why can’t phosphate rock by directly used?

A

it is insoluble meaning plants can’t absorb them and use them as nutrients

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14
Q

what is phosphate treated with to produce soluble salts?

A

-sulfuric acid
-phosphoric acid
-nitric acid

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15
Q

3 reactions

A

-phosphate + nitric acid —> phosphoric acid + calcium nitrate
-phosphate + sulfuric acid —> calcium sulfate + calcium phosphate (single superphosphate)
-phosphate + phosphoric acid —> calcium phosphate (triple superphosphate)

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16
Q

what can the phosphoric acid, produced by phosphate and sulfuric acid be used for?

A

reacting with ammonia to make ammonium phosphate

17
Q

3 ammonia equations

A

-ammonia + phosphoric acid —> ammonium phosphate
3NH3 (aq) + H3PO4 (aq) —> (NH4)3 PO4 (aq)
-ammonia + sulfuric acid —> ammonium sulfate
2NH3 (aq) + H2SO4 —> (NH4)2 SO4 (aq)
-ammonia + nitric acid —> ammonium nitrate
NH3 + HNO₃ —> NH₄NO₃