Factors on EQUILIBRIUM Flashcards
What is Le Chatelier’s Principle?
external condition that disrupt the system, equilibrium shift to new equiposition
What is the external condition?
- Catalyst
- Changes of concentration
- Changes of pressure
- Presence of noble gas ( P increase)
- Changes in Temperature
Does catalyst affect Kc or Kp?
No, it only reduce time taken to reach equilibrium
” aA + bB ⇌ cC + dD “
If add more reactant, equi shift to?
to the product ( to the right )
” aA + bB ⇌ cC + dD “
If add more product, equi shift to?
reactant ( left )
” aA + bB ⇌ cC + dD “
Remove reactant, equi shift to?
Reactant ( left )
” aA + bB ⇌ cC + dD “
Remove product, equi shift to?
Product ( right )
Does final position same like initial position?
No
Does amount of [product] or [reactant] after new equi same as amount of [product] or [reactant] initial equilibrium?
No
What happen to rate of reaction when pressure is increase?
Rate of reaction increase
What happen to the pressure when noble gasses is added?
increase
When P increase, equilibrium shift to the side that have ________ number of moles.
lower
When P decrease, equilibrium shift to the side that have ______ number of moles.
higher
Does pressure affect equilibrium Kp?
No
Does changes in pressure affect equilibrium position?
Yes
Does temperature affect equilibrium constant , K?
Yes
When T is increased, does the rate forward and reverse is equal?
no
Given Delta H = +ve
1.Rate of forward equal to?
2.Rate of reverse equal to?
- Endothermic
- Exothermic
Given Delta H = +ve
What happen when T is increased?
What happen to the yield?
Explain
- Equi shift to the right ( forward ) to absord heat to lower the T
- concentration of product increase
Given Delta H = +ve
What happen when T is decreased?
What happen to the yield?
Explain
- Equilibrium shift to left ( reverse)
to release heat to increase the T - concentration of reactant increase
Given Delta H = -ve
1.What does forward reaction equal to?
2.What does reverse reaction equal to?
- Exothermic
- Endothermic
Given Delta H = -ve
What happen when T is increased?
What happen to the yield?
- Equilibrium shift to the left ( reverse )
to absorb heat to lower the T - reactant increased
Given Delta H = -ve
What happen when T is decreased?
What happen to the yield?
-Equilibrium shift to the right ( forward ) to release heat to increase the T
- product increased