F6 Biogas Flashcards
What four substrates have big biogas potential in Sweden?
Crop residues
Manure
Industrial waste
Food waste
Definition of biogas process/anaerobic digestion
It is i biological engineering process in which complex organic matters are converted to methane (CH4) and and carbon dioxide (CO2) by a mixed population of microbes in the absence of oxygen.
Anaerobic environments in nature with low oxygen levels
Sea sediments (sediment på havsbotten) Wet lands (träskmarker) Ruminating animals (idisslande djur) Rice fields
Pre-requisites (necessities) for biogas production
The flow scheme of anaerobic methane production
Hydrolysis for carbohydrates, protein and fat (speed? and product?)
Environmental factors for anaerobic methane production
- Nutrient requirements: Macro nutrients (C, O, H, N, S, K, Na…)
& Micro nutrients (Fe, Zn, Ni, Cu…) - Toxic compounds (oxygen, heavy metals, organic pollutants, detergents)
- Water activity (>65% water → 35% TS = total solids)
- pH (neutral ca 7-8)
- Redoxpotential (ca -300mV)
- Temperature
- Psychrophilic < 20°C
- Mesophilic ca 35-40°C
- Thermophilic ca 55-60°C
Process temperatures in biogas digesters
Advantages of Thermophilic (60°C) vs Mesophilic (39°C)
Different solid concentrations (TS)
Digestion by “BATCH” method
How is the biogas flow?
What is the usual feedstock (what process)?
CONTINIOUS digester technology
How is the biogas flow?
What is the usual feedstock (what process)?
What are the basic substrate characteristics?
What does HRT stand for?
It stands for Hydraulic Retention Time - theoretical average residence time of a liquid volume in a CSTR (d) (continuous stirred tank reactor)
HRT = V/Qo
V = Digester active volume (m3r)
Qo = volume flow out of the digester (m3/d)
Qi ≈ Qo (for wer fermentation)
What does digester active volume mean?
The active volume, is for ex the sludge volume - normally 80-85% of the total volume.
How long is the HRT (hydraulic retention time)?
ca 15-20 days depending on the substrate characteristics and digester temperature.
20-50 days is normal for mesophilic processes
What does OLR stand for? And what is the mathematical formula?
What is the biogas yield (specific biogas production)?
Nm3 biogas/kg VS (volatile solids)
or
Nm3 biogas/kg wet weight
Expresses how well the substrate is utilised
What is the volumetric biogas production?
m3 biogas /m3 digester volume/d
Expresses how well the digester volume is utilised
Which of carbohydrates, protein and lipids have the highest yield?
Highest → lowest:
Lipids → proteins → carbohydrates
What are the main steps at a biogas plant? And what do they conclude?
Definitions:
Biogas cleaning?
Biogas upgrading?
Biomethane?
Why do we need to upgrade the biogas? And what techniques are there?
Biogas doesn’t meet the requirements of methane volume % → need to upgrade the biogas (remove CO2).
-
Absorption (selective affinity of CO2 solving in a liquid media)
- Water scrubber
- Chemical scrubber (Amine scrubber)
-
Adsorption (selective affinity of CO2 on a media surface)
- Pressure Swing Adsorption (PSA)
-
Gas permeation
- Membranes
- Emerging techniques
- Cryogenic distillation (different boiling point)
What are the principles of absorption (water scrubbing)?
Liquified biomethane/biogas (LBG) +/-
Compressed biomethane/biogas (CBG) +/-