Extent of chemical reactions Flashcards

1
Q

Equilibrium

-

A

When the rate of the forward reaction = the rate of the backwards reaction
In a closed system

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2
Q

Small k vaule (equilibrium constant) means?

Large k vaule (equilibrium constant) means?

A

Little forward reaction

Strong forward reaction

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3
Q

What is homogeneous equilibrium

A

When we have equilibrium reaction that involves species all in the same state

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4
Q

Concentration-time graphs feature

A

The forward reaction drops from its high value as the back reaction rises from its low value until the rate of forward and back is equal.

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5
Q

Reaction quotient and equilibrium concentration

What is Qc (reaction quotient)

A

Used to cal the relationship between the concentration of products and reaction during any stage of the reaction.

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6
Q

Reaction quotient and equilibrium concentration

What does Kc=Qc mean

A

Equilibrium reached

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7
Q

Kc is only affected by…?

A

Temperature

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8
Q

Equilibrium constant

If Kc > 10^4 the equilibrium contains alot of
If Kc < 10^-4 the equilibrium contains alot of

A

Products

Reactants

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9
Q

If Q>K the _____ reaction is preferred until equilibrium is reached
If Q

A

Reverse

Forward

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10
Q

Whats the formula of Q and K

A

K=Products^x
————–
Reactants^y

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11
Q

What compound isnt counted in the Kc and Qc constant

A

H2O

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12
Q

What is the M of B^2
——
A

A

M x M
——— = M
M

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13
Q

Ice calculations

A

I initial
C Ep change
——————–
E Equilibrium Note if 1:1 have same initial M

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14
Q

Position of equilibrium

What is the Le Chatelier’s Principle

A

If a system in equilibrium is subject to a change, the system will act as to partially oppose that change

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15
Q

Position of equilibrium

Endothermic reaction, K _____ with temperature
Exothermic reaction, K ______ with temperature.

A

Increases

Decreases

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16
Q

Changes on equilibrium

Decreasing pressure by increasing volume (gases)
Adding a catalyst
Adding an inert gase
Adding water (dilution)
Increasing temp for exothermic
Increasing temp for endo
Adding reactants 
Adding products 

Whats the effect of change on equilibrium position

A
Shifts in direction of most particles
no change
no change
Shifts direction of most particles
left
right
Right
left
17
Q

Volume increase favors….?

Volume decrease favors..?

A
Forward reaction (wants higher concentration)
Backwards reaction (wants lower concentration)
18
Q

Look at edrolo CO poisoning

A

Dooooo it