Extent of chemical reactions Flashcards
Equilibrium
-
When the rate of the forward reaction = the rate of the backwards reaction
In a closed system
Small k vaule (equilibrium constant) means?
Large k vaule (equilibrium constant) means?
Little forward reaction
Strong forward reaction
What is homogeneous equilibrium
When we have equilibrium reaction that involves species all in the same state
Concentration-time graphs feature
The forward reaction drops from its high value as the back reaction rises from its low value until the rate of forward and back is equal.
Reaction quotient and equilibrium concentration
What is Qc (reaction quotient)
Used to cal the relationship between the concentration of products and reaction during any stage of the reaction.
Reaction quotient and equilibrium concentration
What does Kc=Qc mean
Equilibrium reached
Kc is only affected by…?
Temperature
Equilibrium constant
If Kc > 10^4 the equilibrium contains alot of
If Kc < 10^-4 the equilibrium contains alot of
Products
Reactants
If Q>K the _____ reaction is preferred until equilibrium is reached
If Q
Reverse
Forward
Whats the formula of Q and K
K=Products^x
————–
Reactants^y
What compound isnt counted in the Kc and Qc constant
H2O
What is the M of B^2
——
A
M x M
——— = M
M
Ice calculations
I initial
C Ep change
——————–
E Equilibrium Note if 1:1 have same initial M
Position of equilibrium
What is the Le Chatelier’s Principle
If a system in equilibrium is subject to a change, the system will act as to partially oppose that change
Position of equilibrium
Endothermic reaction, K _____ with temperature
Exothermic reaction, K ______ with temperature.
Increases
Decreases