Exam Cards - Unit 1: Electrons, Bonding & Structure Flashcards

1
Q

Define atomic orbital.

A

A space in which two electrons with opposite spins can inhabit.

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2
Q

Within a shell, state the number of s-, p-, d-, and f-orbitals.

A

s = 1
p = 3
d = 5
f = 7

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3
Q

How many electrons can an orbital hold?

A

2

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4
Q

Define sub-shell.

A

A group of the same type of atomic orbitals within a shell.

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5
Q

Define principle quantum number.

A

A number representing the relative overall energy of each orbital, which increases with distance from the nucleus.

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6
Q

What is the first ionisation energy of an element?

A

The energy needed to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions.

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7
Q

Which three factors affect the nuclear attraction experienced by an electron?

A

Atomic radius, nuclear charge, and electron shielding/screening (inner shells of electrons repel outer-shell electrons).

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8
Q

What is the second ionisation energy of an element?

A

The energy needed to remove one electron from each ion in one mole of gaseous 1+ ions to form one mole of gaseous 2+ ions.

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9
Q

Define ionic bond.

A

An electrostatic attraction between two oppositely charged ions.

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10
Q

Why are ionic compounds able to conduct electricity when molten or dissolved?

A

The ions in a liquid are free to move and they carry a charge.

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11
Q

Why do ionic compunds have high melting points?

A

They are held together by strong electrostatic forces, so it takes high amounts of energy to overcome these forces.

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12
Q

Why do ionic compounds tend to dissolve in water?

A

Water molecules are polar so they pull ions away from the lattice, causing it to dissolve.

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13
Q

Define covalent bond.

A

The sharing of electrons between atoms.

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14
Q

Define a dative covalent bond.

A

A shared pair of electrons which has been provided by one of the bonding atoms only.

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15
Q

Define allotrope.

A

Different forms of the same element in the same state (e.g. diamond and graphite)

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16
Q

What structure do metal elements have?

A

Giant metallic lattice structures.

17
Q

Define metallic bonding.

A

When positive metal ions are attracted to the delocalised negative electrons, forming a lattice of metal ions and a ‘sea’ of delocalised electrons.

18
Q

How does the number of delocalised electrons affect the melting point of a metal?

A

More delocalised electrons per metal ion cause the metallic bonding to be stronger.

19
Q

Why are metals good electrical conductors?

A

The delocalised electrons can carry a current.

20
Q

Which is the strongest intermolecular force?

A

Hydrogen bond.

21
Q

Define Van der Waals forces.

A

Attraction between induced dipoles of neighbouring molecules.