Exam 5 Flashcards

1
Q

Metal with nonmetal

A

Ionic

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2
Q

Nonmetals with nonmetals or metalloids

A

Covalent

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3
Q

Metals interacting to form the metallic material

A

Metallic

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4
Q

Metals have low

A

Ionization energies

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5
Q

Nonmetals have high

A

Electron affinities

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6
Q

What is lattice energy defined as; ie, electrostatic attraction in ionic compounds

A

Energy required to separate one mole of the ionic compound into its gaseous ions

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7
Q

Magniitude of lattice energy and charge on ions have what relationship

A

Direct

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8
Q

Describe Coulombs law

A

Potential energy between two ions is directly proportional to the product of their charges and inversely poportional to the separation between the ions

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9
Q

Equation for Coulombs law

A

PE= (Qcation*Qanion)/r

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10
Q

For singly charged ions, lattice energy and ion size have what relationship

A

Inverse

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11
Q

What is a resonance structure

A

Uses 2 or more Lewis stuctures to represent a particular molecule or ion

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12
Q

Electronegativity greatest where

A

Top right

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13
Q

Lattice energy greatest where

A

Top left

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14
Q

More electronegative means electrons will go towards it

A

More

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15
Q

Dipole of covalent bonds means what

A

Polar, bond has two poles

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16
Q

When two different elements form a covalent bond, the bond is

A

Polar

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17
Q

How to calculate formal charge

A

(valence e- in free atom) - (total # of nonbonding e-) - 1/2 (total # of bonding e-)

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18
Q

Bond dissociation energy definition

A

Enthalpy change required to break a particular bond in one mole of gaseous molecules

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19
Q

How to figure out the enthalpy of reaction from the average bond enthalpies

A

(sum of bonds broken) - (sum of bonds formed)

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20
Q

The Valence-Shell electron pair repulsion (VESPR) model is used to predict molecular geometries based on minimizing what between electron pairs on a central atom

A

Repulsions

21
Q

Angle for linear shape

A

180 degrees

22
Q

Angle for trigonal planar

A

120 degrees

23
Q

Angle for tetrahedral

A

109.5 degrees

24
Q

Angle for trigonal bipyramidal

A

Equotorial is 120 degrees, axial 90 degrees

25
Angle for octahedral
90 degrees for adjacent F-S-F bonds
26
2 e- pairs, AB2
Linear
27
3 e- pairs, AB3
Trigonal planar
28
4 e- pairs, AB4
Tetrahedral
29
5 e- pairs, AB5
Trigonal bipyramidal
30
6 e- pairs, AB6
Octahedral
31
AB2E
Trigonal planar, bent
32
AB2E2
Tetrahedral, bent
33
AB3E
Tetrahedral, trigonal pyramidal
34
AB4E
Trigonal bipyramidal, seesaw
35
AB3E2
Trigonal bipyramidal, T-shaped
36
AB2E3
Trigonal bipyramidal, linear
37
AB5E
Octahedral, square pyramidal
38
AB4E2
Octahedral, square planar
39
If dipoles cancel out, even with covalent bonds between different atoms, the molecule is
Nonpolar
40
Number of hybrid orbitals is what added up
of bonded atoms and the # of lone e- pairs on a central atom
41
Linear hypridization
sp
42
Trigonal planar hybridization
sp2
43
Tetrahedral hybridization
sp3
44
Trigonal bipyramidal hybridization
sp3d
45
Octahedral hybridization
sp3d2
46
Single bonds are
sigma
47
Double bonds are
sigma & pi
48
Triple bonds are
sigma & 2 pi