Exam 3 Chapter 9 Flashcards
diffusion
process by which molecules disperse in space in response to differences in concentration is called
net movement of species from high to low concentration areas takes place. In a closed environment, diffusion will ultimately result in equal concentrations of gas throughout
rate of diffusion
the amount of gas passing through some area per unit time:
rate of diffusion=amount of gas passing through an area/unit of time
effusion
the escape of gas molecules through a tiny hole such as a pinhole in a balloon into a vacuum
Graham’s law of effusion
The rate of effusion of a gas is inversely proportional to the square root of the mass of its particles:
rate of effusion A/rate of effusion B =
sqrt(molar mass B) / sqrt(molar mass A)
Root Mean Square Velocity of a Gas
Root Mean Square molecular speed (u)
speed of molecule with average kinetic energy
u = sqrt(3RT/M)
where M = molar mass in kg/mole
R, gas constant but uses different units (8.314 J/Kmole)
J = (kgm^2)/sec^2
Van der Waal’s Equation
(P+n^2a/v^2)(v-nb)=nRT
where the values of a and b are experimentally determined
Conditions of an Ideal Gas
Gases are most likely to behave ideally at LOW PRESSURES and HIGH TEMPERATURES because particles are moving faster and are farther apart
When do gases deviate from ideal?
At HIGH PRESSURE and LOW TEMPERATURE
Ideal Gas Law
PV = nRT
Potential Energy
PE = mgh