EXAM 3 ch 12 Flashcards

1
Q

Quartz, a form of SiO2, which contains an ordered array of neutral, covalently bonded nonmetal units, is an example of

a molecular solid.
an ionic solid.
a metallic solid.
an amorphous solid.
an alloy.

A

a molecular solid

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2
Q

Obsidian, a form of SiO2, which contains no long-range ordering of any kind and is made up of bonded nonmetal units, is an example of

a molecular solid.
an ionic solid.
a metallic solid.
an amorphous solid.
an alloy.

A

an amorphous solid

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3
Q

Copper has a face-centered cubic unit cell. Which element do you also expect to have a face-centered cubic unit cell?

Na
K
Ti
Mg
Ag

A

Ag

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4
Q

Arrange the following metals in order of expected increasing density. All have a face-centered cubic unit cell.

Ni, Pd, Pt
Pt < Pd < Ni
Pt < Ni < Pd
Pd < Pt < Ni
Pd < Ni < Pt
Ni < Pd < Pt

A

Ni < Pd < Pt

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5
Q

What type of crystal structure produces an aaaaaa layering pattern?

hexagonal
body-centered cubic
face-centered cubic
hexagonal or body-centered cubic
simple cubic

A

simple cubic

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6
Q

n the sodium chloride unit cell, the chloride ions form a cube in which each side is arranged like the following figure. The circles represent the positions of the chloride ions on one square face of the cube. All the other faces are the same. What is the name of this unit cell?

simple cubic
x-face cubic
chloride-centered cubic
body-centered cubic
face-centered cubic

A

face-centered cubic

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7
Q

Which of the following statement(s) about the simple cubic unit cell is(are) correct?

It results from the square packing of atoms in layers.
The atoms lie at the corners of a cube.
Each atom has 6 nearest neighbors.
The stacking pattern can be represented by aaaa.
All these statements are correct.

A

All these statements are correct

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8
Q

In the cesium chloride unit cell shown, the cesium ions sit on the corners of a cube. What is the name of this unit cell?

simple cubic
cubic-centered
chloride-centered cubic
body-centered cubic
face-centered cubic

A

body-centered cubic

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9
Q

Which of the following unit cells has the lowest packing efficiency?

simple cubic
face-centered cubic
body-centered cubic
both face-centered and body-centered cubic
Simple, face-centered, and body-centered cubic all have the same packing efficiency.

A

simple cubic

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10
Q

Which of the following unit cells has the highest packing efficiency?

simple cubic
face-centered cubic
body-centered cubic
both face-centered and body-centered cubic
Simple, face-centered, and body-centered cubic all have the same packing efficiency.

A

face-centered cubic

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11
Q

How many nearest neighbor atoms are there around each atom in a simple cubic unit cell?

4
10
6
12
8

A

6

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12
Q

How many nearest neighbor atoms are there around each atom in a face-centered cubic unit cell?

4
10
6
12
8

A

12

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13
Q

How many nearest neighbor atoms are there around each atom in a body-centered cubic unit cell?

4
10
6
12
8

A

8

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14
Q

An atom in a particular unit cell has 8 nearest neighbor atoms around it. Which unit cell(s) is(are) possible?

simple cubic
hexagonal
body-centered cubic
face-centered cubic or hexagonal
face-centered cubic

A

body-centered cubic

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15
Q

Polonium crystallizes in a simple cubic pattern. How many polonium atoms are in each unit cell?

1
4
2
5
3

A

1

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16
Q

Iron crystallizes in a body-centered cubic pattern. How many iron atoms are in each unit cell?

1
8
2
9
4

A

2

17
Q

Copper crystallizes in a face-centered cubic pattern. How many copper atoms are in each unit cell?

2
12
4
14
8

A

4

18
Q

Silver crystallizes with a face-centered cubic unit cell. The edge length is 408 pm. What is the volume of this unit cell?

7.68 × 107 pm3
9.87 × 107 pm3
6.79 × 107 pm3
3.88 × 107 pm3
8.67 × 107 pm3

A

6.79 × 107 pm3

19
Q

Nickel (Ni) crystallizes as a face-centered unit cell with an edge length of 382 pm. What is the atomic radius of nickel?

135 pm
252 pm
165 pm
1080 pm
191 pm

A

135 pm

20
Q

Iron (Fe) crystallizes as a body-centered unit cell and has an atomic radius of 126 pm. What is the edge length for the unit cell of iron?

55 pm
291 pm
63 pm
356 pm
252 pm

A

291 pm

21
Q

Gold has a face-centered cubic structure with a unit cell edge length of 407.8 pm. What is the contribution to the density from each individual gold atom?

21.44 g/cm3
6.55 g/cm3
26.20 g/cm3
19.28 g/cm3
13.1 g/cm3

A

19.28 g/cm3

22
Q

Which statement regarding the formation of an alloy is correct?

Carbon forms an interstitial alloy with iron because their atomic radii are about the same.
Carbon forms a substitutional alloy with iron because their atomic radii are about the same.
Carbon forms an interstitial alloy with iron because carbon has a much smaller atomic radius.
Carbon forms a substitutional alloy with iron because carbon has a much smaller atomic radius.
Carbon forms an interstitial alloy with iron because carbon has a much larger atomic radius

A

Carbon forms an interstitial alloy with iron because carbon has a much smaller atomic radius.

23
Q

Which of the following refers to an alloy in which the composition is variable and the elements have comparable radii?

intermetallic
substitutional
interstitial
homogeneous
stoichiometric

A

substitutional

24
Q

In addition to carbon and iron, stainless steel contains

teflon and polyethylene.
chromium and nickel.
gold and silver.
platinum.
copper and nickel.

A

chromium and nickel.

25
Q

Bronze that is composed of 10% tin and 90% copper is

a substitutional alloy.
a colloidal alloy.
an interstitial alloy.
an intermetallic compound.
a doped semiconductor.

A

a substitutional alloy.

26
Q

The cubic unit cell of rhenium trioxide (ReO3) has Re atoms at the corners and O atoms on each of the 12 edges. The atoms touch along the edges. The radii are Re 137 pm and O 73 pm. What is the density of ReO3?

2.55 g/cm3
5.25 g/cm3
2.94 g/cm3
7.52 g/cm3
3.49 g/cm3

A

5.25 g/cm3

27
Q

Potassium bromide crystallizes in the rock salt structure. It has a density of 2.75 g/cm3. What is the edge length of the unit cell? In the rock salt structure, the bromide ions form an face-centered cubic unit cell, and the potassium ions occupy the octahedral holes.

  1. pm
  2. pm
  3. pm
  4. pm
  5. pm
A
  1. pm
28
Q

Different structural forms of the elements are called

polymers.
isoforms.
allotropes.
polymorphs.
isotopes.

A

allotropes.

29
Q

How many carbons are bonded to each carbon in graphite?

1
4
2
Some have 2, and some have 3.
3

A

3

30
Q

An approximately spherical allotrope of carbon containing 60 or 70 atoms is

spherohexadecalene and spheroheptadecalene.
spheralene-60 and spheralene-70.
fullerene.
graphitolene.
soccerene.

A

fullerene.

31
Q

The hybridization of atomic orbitals in diamond is

none, since it is the element.
sp3.
sp.
dsp3.
sp2.

A

sp3.

32
Q

The hybridization of atomic orbitals in graphite is

none, since it is the element.
sp3.
sp.
dsp3.
sp2.

A

sp2

33
Q
A