Exam 3 Flashcards

1
Q

Color is related to

A

wavelength and frequency

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2
Q

temperature is related to

A

energy

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3
Q

quantum

A

fixed quantity fo energy

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4
Q

ground state

A

when atom is in its lowest energy state

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5
Q

Heisenberg’s Uncertainty Principle

A

It is not possible to know both the position and momentum of a moving particle at the same time

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6
Q

Principal Quantum Number

A

(n) relative size of the orbital and relative distance from the nucleus; describes overall energy

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7
Q

Angular Momentum Quantum Number

A

(l) indicates the shape of the orbital; defines subshells or sublevels

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8
Q

Magnetic Quantum Number

A

(ml) indicates the spatial orientation of the orbital

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9
Q

Electron Spin Quantum Number

A

(ms) electrons going in opposite directions

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10
Q

Pauli Exclusion Principle

A

no two electron in the same atom can have the same four quantum numbers; each orbital may have 2 electrons with opposing spins

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11
Q

Aufbau Principle

A

electrons are always placed in the lowest energy sublevel available

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12
Q

Hund’s rule

A

when orbitals of equal energy are available, the lowest energy electron configuration has the maximum number of unpaired electrons with parallel spins

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13
Q

exceptions to expected electron configurations in period 4

A

Cr, Cu; will have half or fully filled d orbital and only 1 in the 4s

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14
Q

inner core electrons

A

those held in common with previous noble gas and any completed transition series

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15
Q

outer electrons

A

those in the highest energy level

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16
Q

valence electrons

A

involved in forming compounds

17
Q

octet rule

A

when atoms bond, they lose, gain, or share electrons to attain a filled outer level of 9 electrons (or 2 for H and Li)

18
Q

Where is hydrogen on the electronegativity scale?

A

Between B and C; why we think of C-H bonds as nonpolar

19
Q

Which elements can never be central atoms and only have one bond?

A

H, F

20
Q

bond order

A

the number of electron pairs being shared by a given pair of atoms

21
Q

bond energy

A

energy needed to overcome the attraction between the nuclei and the shared electrons; (stronger bond= higher bond energy)

22
Q

bond length

A

distance between nuclei of the bonded atoms; (longer the bond, weaker the bond)

23
Q

resonance structures

A

have the same relative placement of atoms but different locations of bonding and lone electron pairs

24
Q

What do resonance structures often have due to partial bonding?

A

fractional bond orders; number of shared electron pairs/ number of atoms central atom is bonded to

25
Q

sigma bond

A

the first bond between two atoms involving single overlap of atomic orbitals

26
Q

pi bond

A

the second or third bond between two atoms involving additional overlap of atomic orbitals