EXAM 2 Chem Flashcards

1
Q

what will happen earn 2 identical waves that are out of phase when combin

A

zero amplitude

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2
Q

most significant conclusion to be drawn from the observation of the photoelectric effect

A

the light is contained in discrete packages of energy

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3
Q

ground state of electron confg of oxygen

A

1s2 2s2 2p4

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4
Q

How many atoms of uranium are there in 3.02 moles of this substance?

A

1.82 × 1024 atoms

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5
Q
The mineral zircon contains the following elements in the mass proportions indicated:
49.8% Zr
15.3% Si
34.9% O
What is the empirical formula of zircon?
A

ZrSiO4

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6
Q

According to the Bohr model of the atom, when does the energy of an electron in an atom decrease?

A

When the charge of the nucleus increases or the quantum number n decreases

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7
Q

What is the difference between a 2s orbital and a 2p orbital?

A

They have different angular momentum quantum numbers.

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8
Q

Which of the following statements correctly describes an observation of the photoelectric effect?

A

There is a frequency of light below which no electrons are emitted.

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9
Q

How many moles of ethanol are contained in 57.38 grams of ethanol (C2H5OH)?

A

1.246 moles ethanol

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10
Q

Which label is most appropriate for the horizontal scale of this diagram of the electromagnetic spectrum?

A

Increasing wavelength

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11
Q

What does the energy of the work-function value represent?

A

The amount of energy required to overcome the attractive forces between an electron and the bulk metal.

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12
Q

What is electron affinity?

A

The energy change that occurs when an atom gains an electron.

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13
Q

What is the ground state electron configuration for fluorine?

A

1s22s22p5

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14
Q

Which of these waves has the greatest amplitude?

A

C the large waves

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15
Q

How does the size of the cation compare to its corresponding atom?

A

The cation is smaller

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16
Q

What is the relationship between acetic acid (C2H4O2 ) and glyceraldehyde (C3H6O3 )?

A

Both molecules have the same empirical formula

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17
Q

Electronegativity describes the ability of an atom to attract additional electron density to itself. Electronegativity would not help predict:

A

Solubility of a substance in water.

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18
Q

Which of the following is a consequence of the Heisenberg uncertainty principle?

A

The exact path taken by an electron cannot be determined, only its probable path.

19
Q

Which of the following is the least electronegative element and the most electronegative element, respectively?

A

francium, fluorine

20
Q

When the mass percent of each element making up an unknown compound is given, what other information is needed to determine the empirical formula?

A

the molar mass of each element

21
Q

Why does a sheet of paper appear white?

A

because it reflects all wavelengths of visible light

22
Q

Which of the following is a correct statement of Hund’s Rule?

A

Electrons will occupy separate degenerate orbitals and maintain parallel spins before pairing up.

23
Q

For a given element, how does the size of the anion compare to the size of the atom?

24
Q

What happens to the size of an atom when it loses an electron?

A

The atom becomes smaller

25
How many molecules of carbon dioxide are found in 2.50 moles of carbon dioxide?
1.51 × 1024 molecules
26
What is the electron configuration of the oxide ion (O2− )
1s22s22p6
27
What is the ground state electron configuration for boron
1s22s22p1
28
Which of the following is the general periodic trend for increasing electron affinity
up and right
29
How many atoms are contained in 1.00 mole of water?
18.0 × 1023 atoms
30
An unknown pesticide is made up of 18.28% carbon, 0.77% hydrogen, and 80.95% chlorine. What is the empirical formula of the pesticide?
C2HCl3
31
What happens to the ionization energy as the size of the nucleus increases
It increases.
32
How many moles are represented by 3.75 × 1021 atoms of iron?
6.23 × 10−3 moles Fe
33
when two waves combine what do they make
larger one
34
Under what circumstances does the Bohr model fail to make accurate predictions of an atom’s spectra?
When the number of electrons in the atom is greater than 1
35
An atom of helium has a de Broglie wavelength of 4.3 × 10−12 meter. What is its velocity?
2.3 × 104 m / s
36
What is the reason that conversion from grams to moles is useful?
Balanced chemical reactions relate to numbers of reactant molecules, not to masses of reactant molecules
37
What is the maximum number of electrons that may be found in a 3p energy sublevel?
6
38
Why is it possible to predict the momentum of a golf ball much more accurately than that of an electron?
The energy of the photons used to observe a golf ball is small compared to the energy of the golf ball.
39
To what does the “ultraviolet catastrophe” refer?
The catastrophic implications for turn-of-the-century physics of the absence of ultraviolet light in the emission spectrum of a black body.
40
Which of the following best describes incandescence?
The electromagnetic radiation emitted by an object when it is heated.
41
In 1900, which of the following did Max Planck propose in order to solve the ultraviolet catastrophe?
He proposed that in a heated body, a discrete amount of energy is absorbed by the multiple oscillators.
42
A great deal of time and effort has been put into trying to locate the electrons in an atom. Why is it important to understand where the electrons are?
Knowing where the electrons are allows prediction and understanding of how atoms come together to form molecules.
43
What is the most significant conclusion to be drawn from the observations of the photoelectric effect?
That light is contained in discrete packages of energy.