Exam 2 Flashcards
Balanced Chemical Equation
Every atom on the reactant side ends up on the product side. Vice versa.
Limiting Reagent
Reactant in the shortest supply limits the amount of product
Excess Reagent
Reactant with excess amount after the reaction
Percent Yield
Actual Yield/ Theoretical Yield * 100
Solution
a homogenous mixture of two or more substances in which the ions or molecules intermingle freely
Solvent
component of a solution present in the largest amount. It is the medium into which solutes are mixed or dissolved.
Solute
Substance dissolved in the solvent.
Concentration
Ratios between the solute, solvent, and solution.
Dilute Solution
Has a small solute-solvent ratio
Concentrated Solution
Has a large solute-solvent ratio
Saturated Solution
Limit to how much solute can go into a solvent. When amount of solute added exceeds the limit, solution is saturated.
Unsaturated Solution
Less solute present than required for saturation.
Solubility and Temperature
Directly proportional. Increase temperature, increase solubility. Sometimes can dissolve MORE solute by heating the mixture. i.e. sugar water vs. simple syrup
Supersaturated Solution
Solution that contains more solute than required for saturation at a given temperature. Usually unstable.
Precipitation Reactions
Reactions that form precipitates
Electrolyte
a compound that conducts electricity either in solution or in a molten state.
Dissociation of Ionic Compound
Particles surrounded by solvent
Nonelectrolytes
aqueous solutions of most molecular compounds that do not conduct electricity
Hydrated
When a solute particle is surrounded by water
Ionic Equation
All soluble strong electrolytes are written in dissociated form.
Spectator Ions
Ions present in the reaction that do not participate.
Net Ionic Equation
Ionic equation without spectator ions. Allow us to generalize/ predict future relations. Charges on each side MUST balance.
Double Replacement Definition
a reaction of two salts in which the cations and the anions switch places.
Types of Replacement (single or double) Rx
gas forming, precipitation, acid-base
Gas forming rx
- Type of replacement
- One product is a gas
Precipitation Rx
- Type of replacement
- use solubility rules
- one product is a solid
Molarity
M
The number of moles of solute per liter of solution
Electrolyte
compound that conducts electricity in solution or molten state
Conductivity
get definition from Pam!
dissociated vs. dissolved
dissociate: break into ions
dissolve: stay in lattice surrounded by H2O
Dissociate
break up into ions
Base
a substance that produces hydroxide in water
Ionization Reaction
reaction that forms ions from neutral reactants
Acid/Water Rx
Acid + H2O –> H3O+ + anion
Monoprotic Acid
Only 1 H+ per molecule of acid
Polyprotic Acid
Many H+ per molecule of acid
Base/Water Rx
Base + H2O –> BaseH+ + OH-
Binary Acids
binary compounds of hydrogen with nonmetals
Oxoacids
acids that contain H, O, and another element
Acid Salt
Salt of a partially neutralized polyprotic acid
Naming Oxoacids
ate –> -ic + acid
ite –> -ous + acid
Naming Binary Acids
‘hydro’ + nonmetal stem + ‘-ic’ acid.
Naming Bases with O2-
(metal) oxide
Strong Acid Definition
acids that are strong electrolytes
Strong Acid List
HClO4- perchloric acid HCL- hydrochloric acid HBr- hydrobromic acid HI- hydroiodic acid HNO3 - nitric acid H2SO4 - sulfuric acid
Strong Base Definition
metal hydroxide that dissociates essentially 100% in water
Strong Bases in Group IIA
Ca(OH)2 - calcium hydroxide
Sr(OH)2 - strontium hydroxide
Ba(OH)2 - barium hydroxide
Mg(OH)2 - magnesium hydroxide
weak electrolyte
substance that has low percent ionization or dissociation in water
weak acid
acid that has low % ionization in solutions, poor proton donor
weak base
base with low % ionization in solution, poor proton acceptor.
forward reaction
L -> R
reverse reaction
R -> L
dynamic equilibrium
- forward and reverse rx occurring at the same rate
- double arrows
chemical equilibrium
dynamic equilibrium of a chemical system
Coulomb’s Law
F = k (q1q2)/(d^2)
ion charge to force
directly proportional
distance to force
inversely proportional
conjugate acid
a base that has gained a proton
conjugate base
an acid that has lost a proton
metal oxide
- strong bases
- deprotonate water to make 2OH-
metal hydroxide
metalOH
Molarity
moles of solute / liters of solution
weight percent
(mass solute/ mass solution) * 100
1 ppm
1 mg solute/kg of solution
1 ppb
1 ug (microgram) solute/kg of solution
When preparing solutions
add solid first, then liquid!
Molarity of hydrates
- use H2O in molar mass
- ignore after that
moles in stock =
moles final
moles =
Molarity * Volume (L)
M1V1 =
M2V2